The influence of C 6 H 16 N 2 addition on the microstructural and superconducting properties of MgB 2 was systematically investigated. Unlike previously reported carbon sources, the C 6 H 16 N 2 additive had no effect on the lattice parameters of MgB 2 . However, the obvious improvement of critical current density (J c ) was obtained for C 6 H 16 N 2 added MgB 2 without carbon substitution for boron. The average grain size was reduced with the addition of C 6 H 16 N 2 . Additionally, different numbers of spherical MgB 2 grains appeared inside the C 6 H 16 N 2 added MgB 2 . As the added amount of C 6 H 16 N 2 increased, the active cross-sectional area fraction (A F ) values first increased then decreased. The possible reasons for these results have been discussed. The additive C 6 H 16 N 2 resulted in a small depression in T c and slightly increased the ∆T c of MgB 2 at 0 T. The H c2 (T) and H irr (T) values of C 6 H 16 N 2 added MgB 2 samples are larger than those of pure MgB 2 at temperatures below 25 K. It was concluded that the reduced grain size and the improved grain connectivity were mainly correlated with the enhancement of the J c , F p , H c2 , and H irr performances in C 6 H 16 N 2 added MgB 2 superconductors.