2022
DOI: 10.1016/j.cej.2022.138027
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Effect of ball milling with hydrogen peroxide or ammonia hydroxide on sorption performance of volatile organic compounds by biochar from different pyrolysis temperatures

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Cited by 46 publications
(13 citation statements)
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“…Moreover, the pseudo-first order models (R 2 = 0.987-0.994) fitted the data lightly greater than pseudo-second order models (R 2 = 0.967-0.973) for the adsorption of TCC, which implied that the pore diffusion process was the rate-limiting step (Supplementary Table S3; Alberti et al, 2012). It was also confirmed that all adsorption rate constants (k 1 ) were much better than k 2 (Supplementary Table S3; Qi et al, 2022). Combined with the results of SEM and BET, BC 700 increased the surface area, pore volume, and pore diameter of biochar compared with BC 300 and BC 500 , which facilitated the diffusion of TCC in the pores of biochar, thus increasing the TCC adsorption efficiency of biochar (Supplementary Figure S1).…”
Section: Determination Of Biochar Adsorption Capacity and Optimizatio...mentioning
confidence: 66%
“…Moreover, the pseudo-first order models (R 2 = 0.987-0.994) fitted the data lightly greater than pseudo-second order models (R 2 = 0.967-0.973) for the adsorption of TCC, which implied that the pore diffusion process was the rate-limiting step (Supplementary Table S3; Alberti et al, 2012). It was also confirmed that all adsorption rate constants (k 1 ) were much better than k 2 (Supplementary Table S3; Qi et al, 2022). Combined with the results of SEM and BET, BC 700 increased the surface area, pore volume, and pore diameter of biochar compared with BC 300 and BC 500 , which facilitated the diffusion of TCC in the pores of biochar, thus increasing the TCC adsorption efficiency of biochar (Supplementary Figure S1).…”
Section: Determination Of Biochar Adsorption Capacity and Optimizatio...mentioning
confidence: 66%
“…However, the pore collapse decreased the specific surface area when the pyrolysis temperature exceeded 800 °C and weakened the adsorption capacity of the adsorbent. [35] In addition, the phosphate adsorption performance of the tobacco stem-based biochars prepared at 800 °C with different raw material particle sizes was also determined. Biochars prepared with a raw material particle size < 2 mm showed no significant difference in phosphate adsorption capacity and removal rate, but these significantly decreased when the raw material particle size was > 2 mm.…”
Section: Adsorption Performancementioning
confidence: 99%
“…25 Ball milling in atmospheres or combination with other chemicals may influence the surface functional groups of adsorbent, thus altering its ability to adsorb different pollutants. 26 For instance, ball-milled biochar was modified with hydrogen peroxide (H 2 O 2 ) and ammonia hydroxide (NH 3 ·H 2 O), effectively changing the morphological characteristics and improving its adsorption capacity for aromatic volatile organic chemicals. 27 However, using H 2 O 2 as a modifier in combination with ball milling for physical-chemical modification is still at a preliminary stage, especially in the field of pharmaceuticals removal.…”
Section: Introductionmentioning
confidence: 99%