A single-stage basin solar still augmented with flat-plate solar collector was investigated to examine the effect of the available amount of exergy on still production. For different temperatures, solar intensities, and distilled water production, the quantity of exergy was computed. Calculations were performed based on experimental measurements and readings for various weather and operational conditions. The total distilled water produced from the collector augmented still is found to be 1807 ml/day which is 77 % larger than that when the still worked without collector (1016 ml/day).