Fossil fuels are a leading source of global warming pollution. Even the waste products are hazardous to public health and the environment. Considering the business cost and environmental concerns, the technology of 'Bio-waste-to-Energy' is recognized as an increasingly important renewable source of energy. Here we have produced potassium hydroxide (KOH) activated microporous carbon from tea wastage. We have fabricated flexible Polyvinyl alcohol (PVA: easily processable, cheap and eco-friendly polymer) based films using Activated Carbon (AC) as nanofiller with different weight percentage. Conductivity observation of the sample was done to study their prospect as the dielectric materials in energy storage, microwave absorption applications. Depending upon the results, we can apply the Activated Carbon (AC) based polyvinyl alcohol (PVA) dielectric film to make flexible, environmental friendly energy/storage devices, microwave absorbents.