“…The best performances for nanosized ZnO can be reached either modifying the strategy of synthesis 14 or doping the material with different species, including transition metals (Mn, Cu) but also rare earth elements (La, Er) 15,16 . Also bismuth has been tested as dopant, proving its ability to shift the adsorption edge of ZnO (reducing the band gap of the material) to lower energy, exploiting solar light and modifying the separation rate of photoinduced charge carriers [17][18][19] . Bismuth is a great alternative to noble metals since it is cheaper, non-toxic and environmentally friendly material; besides, it is also able to favour trapping of photo-generated electrons, reducing the rate of recombination processes between electrons and holes 20-22 . In the present paper a study on both bare (a commercial oxide available by Sigma Aldrich) and bismuth doped ZnO nanopowders (obtained by impregnation of the commercial one with Bi/Zn molar ratios in the range 0.01-0.03) was performed with the aim of photodegrading o-toluidine.…”