Effect of Bismuth on hydrogen storage properties of melt-spun LaNi4.7-x Al0.3Bix (x = 0.0, 0.1, 0.2, 0.3) ribbons

Yılmaz, Fikret; Ergen, Semra; Hong, Soon‐Jik; Uzun, Orhan

doi:10.1016/j.ijhydene.2018.07.090

International Journal of Hydrogen Energy

2018

DOI: 10.1016/j.ijhydene.2018.07.090

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Effect of Bismuth on hydrogen storage properties of melt-spun LaNi4.7-x Al0.3Bix (x = 0.0, 0.1, 0.2, 0.3) ribbons

Fikret Yılmaz

Semra Ergen

Soon‐Jik Hong

et al.

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Cited by 13 publications

References 28 publications

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Intermetallic Compounds for Hydrogen Storage: Current Status and Future Perspectives

Paul,

Mehla,

Bhargava

2024

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Intermetallic compounds are an emerging class of materials with intriguing hydrogen activation and storage capabilities garnering attention for their application in low‐temperature hydrogen storage and metal hydride batteries. However, none of the existing intermetallic compounds have met the gravimetric hydrogen storage capacity target of 5.5 wt.%. Some A2B‐type intermetallic compounds, like Mg2Ni, Mg2Co, and Mg2Fe, approach this target but require high temperatures for hydrogen desorption limiting their use in low‐temperature hydrogen storage and automotive applications. Conversely, some intermetallic compounds like ZrV2 and LaNi5, exhibit hydrogen desorption at ambient conditions but with comparatively lower hydrogen storage capacities. This review article provides a comprehensive account of the different types of intermetallic compounds, their synthesis using different solidification‐based and solid‐state diffusion‐based approaches, and their metallurgical and structural properties. It examines the complex interdependencies between the structural parameters of intermetallic compounds and hydrogen storage performance. A definitive but non‐linear correlation is identified between void volume and gravimetric hydrogen storage capacities while lattice structure, evolution of lattice structure with hydrogen absorption, enthalpy of hydride formation, and hydrogen activation reactivities of intermetallic compounds are identified as critical parameters governing hydrogen storage performance.

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Intermetallic Compounds for Hydrogen Storage: Current Status and Future Perspectives

Paul,

Mehla,

Bhargava

2024

Small

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Stability of LaNi5-Co alloys cycled in hydrogen — Part 1 evolution in gaseous hydrogen storage performance

Zhu

et al. 2019

International Journal of Hydrogen Energy

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On structural model of AB5-type multi-element hydrogen storage alloy

Panwar¹,

Srivastava²

2019

International Journal of Hydrogen Energy

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Effect of Bismuth on hydrogen storage properties of melt-spun LaNi4.7-x Al0.3Bix (x = 0.0, 0.1, 0.2, 0.3) ribbons

Cited by 13 publications

References 28 publications

Intermetallic Compounds for Hydrogen Storage: Current Status and Future Perspectives

Intermetallic Compounds for Hydrogen Storage: Current Status and Future Perspectives

Stability of LaNi5-Co alloys cycled in hydrogen — Part 1 evolution in gaseous hydrogen storage performance

On structural model of AB5-type multi-element hydrogen storage alloy

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