Ferric ion was introduced to the commercial photocatalyst P25 (Degussa) by ultrasonic wet impregnation technique. The concentration of the dopant was varied from 0.0 to 3.0% Fe/Ti ratio. The doped TiO 2 was then loaded to alumina balls using mechanical coating technique and followed by calcination in air at 400, 450, 500 and 550 o C. The fabricated photocatalyst was characterized by X-ray diffraction, N 2 adsorption-desorption isotherms, scanning electron microscopy, UV-Vis diffuse reflectance spectroscopy, X-ray adsorption near edge structure and photoluminescence spectroscopy. The photocatalytic activity was tested by following the degradation of methylene blue (MB). It was found that the Fe 3+ doped TiO 2 /Al 2 O 3 has a combination of anatase and rutile phase and free of iron oxide phases. The optimum calcination temperature is 400 o C with 0.1% Fe 3+ concentration. The catalyst addresses the entrainment in photocatalytic reactors, eliminating the need for a post filtration process.