Effect of calcination temperature and composition on the spray-dried microencapsulated nanostructured SAPO-34 with kaolin for methanol conversion to ethylene and propylene in fluidized bed reactor

Engineering Thermally Resistant Catalytic Particles for Oxidative Coupling of Methane Using Spray-Drying and Incorporating SiC

“…37,38 The resulting advantages of spray-dried catalyst vary from case to case, like the enhanced activity reported for the hydrogenation of toluene, 39 the extended lifetime reported for the methanol-toaromatics 40 or the excellent attrition resistance reported for fluidized-bed reactions such as methanol-to-olefins and crudeto-chemicals. 41,42 In the present study, we have studied the potential benefits of including SiC and using spray drying in the formulation/ engineering of catalytic particles for oxydative couplign of methane. For such a purpose, we have prepared a set of catalysts including a Mn−Na−W/SiO 2 −SiC catalyst using spray drying, and a Mn−Na−W/SiO 2 catalyst using impregnation.…”

“…and physical properties of the precursor solution (i.e., density, viscosity, concentration, etc. ). , The resulting advantages of spray-dried catalyst vary from case to case, like the enhanced activity reported for the hydrogenation of toluene, the extended lifetime reported for the methanol-to-aromatics or the excellent attrition resistance reported for fluidized-bed reactions such as methanol-to-olefins and crude-to-chemicals. , …”

Multiple Cuprous Centers Supported on a Titanium-Based Metal–Organic Framework Catalyze CO2 Hydrogenation to Ethylene

“…In comparison to the industrially relevant catalyst SAPO-34 that produces ethylene through the methanol-to-olefin (MTO) process with ethylene production rates of 9926 μmol g Cat –1 h –1 (measured on a fixed bed reactor) and 11025 μmol g Cat –1 h –1 (measured on a a fluidized bed reactor), , the activity of the MIL-125-NH 2 -Cu I -4 is still low. The future development of catalysts with higher activities is desired.…”

“…In comparison to the industrially relevant catalyst SAPO-34 that produces ethylene through the methanol-to-olefin (MTO) process with ethylene production rates of 9926 μmol g Cat −1 h −1 (measured on a fixed bed reactor) and 11025 μmol g Cat −1 h −1 (measured on a a fluidized bed reactor), 33,34 the activity of the The stability of MIL-125-NH 2 -Cu I -4 was confirmed by its unchanged PXRD patterns after a catalytic reaction for 16 h (Figure S15, purple line). TEM images showed no formation of copper nanoparticles (Cu NPs) after the reaction at 100 °C (Figure 4c).…”

Ultrasound-assisted rapid hydrothermal design of efficient nanostructured MFI-Type aluminosilicate catalyst for methanol to propylene reaction

“…Light olefins especially consist of ethylene (C 2 H 6 ) and propylene (C 3 H 8 ) [4] . The C 2 H 6 /C 3 H 8 ratio of MTO products can vary considerably depending on the catalyst framework type and as well as reaction conditions [5] , [6] , [7] . In this case, methanol to propylene reaction (MTP) with high amount of propylene production seems to be a suitable strategy by increasing world demand for petrochemical plants [8] , [9] , [10] .…”