Effect of carbon on interstitial ordering and magnetic properties of ε-Fe2(N,C)1-

Brink, Bastian; Ståhl, Kenny; Christiansen, Thomas; Frandsen, Cathrine; Hansen, Mikkel Fougt; Béran, P.; Somers, Marcel A. J.

doi:10.1016/j.jallcom.2016.09.317

Cited by 3 publications

(1 citation statement)

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“…Carbonitrides, which are conceived to be solid solution composed of carbides and nitrides, have received considerable attention due to their remarkable physical, chemical, mechanical, and biomedical properties . Recently, carbonitrides have been used as lithium‐ion batteries, soft magnetic materials, high‐temperature electric and heat conductor, oxidation‐resistant, corrosion‐resistant, and wear‐resistant materials . Most importantly, the noticeable advantage of carbonitrides is that the mechanical, optical, and electronic properties can be manipulated by controlling the carbon and nitrogen concentrations …”

Section: Introductionmentioning

confidence: 99%

Influence of carbon on stability, mechanical property, electronic structure, and lattice dynamics of silicon carbonitride

Hua

Zhong

et al. 2018

J Am Ceram Soc

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In this study, first‐principles calculations were performed to study the stability, mechanical property, electronic structure and lattice dynamics of β‐Si3(Cx,N1−x)4 silicon carbonitride. The solubility of carbon in β‐Si3(Cx,N1−x)4 having a stable structure is shown to be about 15 at.%. Within the limit of solubility, an increase in carbon concentration in β‐Si3(Cx,N1−x)4 will lead to a decrease in the Young's modulus and density and an increase in the Poisson's ratio. The study of deformation behavior shows that the most likely slip system of 11¯000001 is on prismatic plane rather than on basal plane. This feature of β‐Si3(Cx,N1−x)4 is similar to WC. In addition, the ductility and fracture toughness of β‐Si3(Cx,N1−x)4 can be optimized by controlling the carbon concentration. The improvement in ductility and fracture toughness can be attributed to the formation of metallic bonds by the incorporation of carbon atoms. The lattice dynamics study shows that the structural stability of β‐Si3(Cx,N1−x)4 is controlled by energy stability criteria under stress‐free condition. In the stressed state, the structural stability of β‐Si3(Cx,N1−x)4 is controlled by the elastic stability criteria. Subsequently, the β‐Si3(Cx,N1−x)4 solid solution was prepared by self‐propagating high‐temperature synthesis (SHS), and the carbon‐concentration‐dependent mechanical properties were consistent with the first‐principles calculations. The maximum fracture toughness of 10.4 MPa·m0.5 was obtained in β‐Si3(Cx,N1−x)4 at carbon concentration of 5 wt%, which means that the solid solution toughening can be used as a supplement to crack bridging toughening and phase transition toughening for ceramic toughening. The results obtained in this study reveal that the β‐Si3(Cx,N1−x)4 solid solution is a promising candidate for high‐speed ceramic bearings.

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Section: Introductionmentioning

confidence: 99%

Influence of carbon on stability, mechanical property, electronic structure, and lattice dynamics of silicon carbonitride

Hua

Zhong

et al. 2018

J Am Ceram Soc

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Enhanced magnetic properties and thermal stability of highly ordered ε-Fe₃N_1+x (−0.12 ≤ x ≤ −0.01) nanoparticles

Pan

Zhou

et al. 2020

Nanoscale

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Influence of carbon on structure stability, mechanical and tribological properties of β-Si₃(C_x,N_1−x)₄ silicon carbonitride

Zhong¹,

Hua²,

Chen³

et al. 2018

Mater. Res. Express

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Effect of carbon on interstitial ordering and magnetic properties of ε-Fe2(N,C)1-

Cited by 3 publications

References 40 publications

Influence of carbon on stability, mechanical property, electronic structure, and lattice dynamics of silicon carbonitride

Influence of carbon on stability, mechanical property, electronic structure, and lattice dynamics of silicon carbonitride

Enhanced magnetic properties and thermal stability of highly ordered ε-Fe₃N_1+x (−0.12 ≤ x ≤ −0.01) nanoparticles

Influence of carbon on structure stability, mechanical and tribological properties of β-Si₃(C_x,N_1−x)₄ silicon carbonitride

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Effect of carbon on interstitial ordering and magnetic properties of ε-Fe2(N,C)1-

Cited by 3 publications

References 40 publications

Influence of carbon on stability, mechanical property, electronic structure, and lattice dynamics of silicon carbonitride

Influence of carbon on stability, mechanical property, electronic structure, and lattice dynamics of silicon carbonitride

Enhanced magnetic properties and thermal stability of highly ordered ε-Fe3N1+x (−0.12 ≤ x ≤ −0.01) nanoparticles

Influence of carbon on structure stability, mechanical and tribological properties of β-Si3(Cx,N1−x)4 silicon carbonitride

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Product

Resources

About

Enhanced magnetic properties and thermal stability of highly ordered ε-Fe₃N_1+x (−0.12 ≤ x ≤ −0.01) nanoparticles

Influence of carbon on structure stability, mechanical and tribological properties of β-Si₃(C_x,N_1−x)₄ silicon carbonitride