Effect of carbonyl and alkoxycarbonyl groups on the direction of the hydrogenolysis of the furan ring under the conditions of vapor-phase hydrogenation

Bel'skii, I. F.; Shuikin, N. I.; Shostakovskii, V. M.

doi:10.1007/bf00920269

Cited by 3 publications

(3 citation statements)

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“…Other catalyst systems of PtO 2 with FeCl 2 and Pt/Co 2 AlO 4 are also known to catalyze the hydrogenolysis of furfural, but these methods suffer from low yields of 1,2-PeD (below 30%). The development of efficient catalytic systems for the direct transformation of furfural to 1,2-PeD would thus be very beneficial . Herein, we report that a catalyst consisting of hydrotalcite-supported Pt nanoparticles (Pt/HT) is capable of efficiently promoting the direct hydrogenolysis of furfural to 1,2-PeD without the presence of any additives.…”

Section: Introductionmentioning

confidence: 99%

Direct Transformation of Furfural to 1,2-Pentanediol Using a Hydrotalcite-Supported Platinum Nanoparticle Catalyst

Mizugaki

Yamakawa

Nagatsu

et al. 2014

ACS Sustainable Chem. Eng.

154

138

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Section: Introductionmentioning

confidence: 99%

Direct Transformation of Furfural to 1,2-Pentanediol Using a Hydrotalcite-Supported Platinum Nanoparticle Catalyst

Mizugaki

Yamakawa

Nagatsu

et al. 2014

ACS Sustainable Chem. Eng.

154

138

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“…Despite the exceptional usefulness of furfural as a C5 resource, the transformation of furfural to 1,2‐PeD has not been widely studied and suﬀers from low yields of 1,2‐PeD (less than 30 %) . Thus, the development of eﬃcient catalytic systems for the direct transformation of furfural to 1,2‐PeD would be very beneficial . We have found that hydrotalcite‐supported Pt nanoparticles (Pt/HT) eﬃciently catalyze the direct hydrogenolysis of furfural to 1,2‐PeD without the presence of any additives (Eq.…”

Section: C−o Bond Cleavagementioning

confidence: 99%

Development of High Performance Heterogeneous Catalysts for Selective Cleavage of C−O and C−C Bonds of Biomass‐Derived Oxygenates

Mizugaki

Kaneda

2018

The Chemical Record

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The environmental impact of CO emissions via the use of fossil resources as chemical feedstock and fuels has stimulated research to utilize renewable biomass feedstock. The biogenic compounds such as polyols are highly oxygenated and their valorization requires the new methods to control the oxygen to carbon ratio of the chemicals. The catalytic cleavage of C-O bonds and C-C bonds is promising methods, but the conventional catalyst systems encounter the difficulty to obtain the high yields of the desired products. This review describes our recent development of the high performance heterogeneous catalysts for the valorization of the biogenic chemicals such as glycerol, furfural, and levulinic acid via selective cleavage of C-O bonds and C-C bonds in the liquid-phase. Selective C-O bond cleavage by hydrogenolysis enables production of various diols useful as engineering plastics, antifreeze, and cosmetics in high yields. The success of the selective C-C bond scission of levulinic acid can be applied to a wide range of the biogenic oxygenates such as carboxylic acids, esters, lactones, and primary alcohols, in which the selective C-C bond scission at adjacent to the oxygen functional groups are achieved. Furthermore, valorization of glycerol by selective acetylation and acetalization, and of levulinic acid by hydrogenation is described. Our catalysts show excellent performance compared to the reported catalysts in the aforementioned valorization.

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“…FFR can be selectively transformed into different furanic compounds [7][8][9] and polyols [10][11][12][13][14][15] which have wide range of commercial and industrial applications (Scheme 1). The selective conversion of FFR into open chain compounds as alcohol or diols received much attention in the last few years due to their wide range of applications in polymer industries for the production of polyester and polyurethanes [16][17][18], as well as for the synthesis of fungicides, disinfectants, and fine chemicals. New green strategies for the production of valuable polyols from biomass are highly desirable, as well as the development of Recently, different monometallic Pd-based materials were deeply studied for furfural hydrogenation.…”

Section: Introductionmentioning

confidence: 99%

Ti-Doped Pd-Au Catalysts for One-Pot Hydrogenation and Ring Opening of Furfural

et al. 2018

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Pd-Au bimetallic catalysts with different Pd/Au atomic ratios, supported on ordered structured silica (Hexagonal mesoporous silica-HMS, or Santa Barbara Amorphous-15-SBA-15) were evaluated for one-pot hydrogenation of furfural to 1,2-pentanediol. The surface and structural properties of the catalysts were deeply investigated by X-ray photoelectron spectroscopy (XPS), X-ray diffraction (XRD), N 2 adsorption isotherms (BET), Infrared spectroscopy (IR), and acid capacity measurements. XPS studies revealed that Ti doped supports had higher dispersion of the active phase, particularly in the case of Pd-Au materials in which Ti played an important role in stabilizing the metallic species. Among the various process conditions studied, such as temperature (160 • C), catalyst amount (10% w/w), and reaction time (5 h), H 2 pressure (500 psi) was found to improve the 1,2-pentanediol selectivity. The SBA silica bimetallic Ti-doped system showed the best performance in terms of stability and reusability, after multiple cycles. Under specific reaction conditions, the synergism between Pd-Au alloy and Ti doping of the support allowed the ring opening pathway towards the formation of 1,2-pentanediol in furfural hydrogenation.

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Effect of carbonyl and alkoxycarbonyl groups on the direction of the hydrogenolysis of the furan ring under the conditions of vapor-phase hydrogenation

Cited by 3 publications

References 1 publication

Direct Transformation of Furfural to 1,2-Pentanediol Using a Hydrotalcite-Supported Platinum Nanoparticle Catalyst

Direct Transformation of Furfural to 1,2-Pentanediol Using a Hydrotalcite-Supported Platinum Nanoparticle Catalyst

Development of High Performance Heterogeneous Catalysts for Selective Cleavage of C−O and C−C Bonds of Biomass‐Derived Oxygenates

Ti-Doped Pd-Au Catalysts for One-Pot Hydrogenation and Ring Opening of Furfural

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