Effect of chemical environment on K shell binding energy of Ag and Sn

Effect of chemical environment on L subshell fluorescence yields using synchrotron radiation

“…values ω 1 , ω 2 and ω 3 are determined using Eqns. (1)- (5). In the determination of ω 1 , ω 2 and ω 3 we have taken Coster-Kronig transition probabilities from Puri et al [30] and the fractional x-ray emission rates from Scofield [29].…”

“…When an atom is in chemical environment, the type of chemical bonding, the oxidation state and coordination number would shift binding energy as well as x-ray emission lines of the atom. Niranjana et al [5][6] have studied the effect of chemical environment on K shell binding energy of Ag and Sn, and Ho and its compounds using bremsstrahlung radiation. They have shown that the shift in K shell binding energy depends on crystal structure.…”

Determination of K shell absorption parameters for some lanthanides using the X-ray attenuation method

“…They observed that positive for Ho 2 O 3 and negative for HoF 3 , indicating the dependence of the chemical shift on the crystal structure. Niranjana et al [33] determined the K edge energies for Ag and Sn in their pure elemental targets and compounds using external bremsstrahlung to understand the effect of crystal structure and oxidation number on K shell binding energy. They observed that positive as well as negative shifts in K shell binding energy for different compounds of the same element.…”