Effect of chemical oxidation of spinel-type LiNi0.5Mn1.3Ti0.2O4 by soaking in HNO3, HCl and H2SO4

Fujimoto, Kenjiro; Kitajima, Yuki; Aimi, Akihisa

doi:10.1016/j.jssc.2021.122366

Cited by 6 publications

(1 citation statement)

References 26 publications

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“…This effect appears to be dependent on material composition and acid choice, however, as Li + /H + exchange was observed in LiNi 0.5 Mn 1.3 Ti 0.2 O 4 when treated with HCl. [ 139 ] Olivine LiFePO 4 exhibits a strong expansion upon H + /Li + exchange, due to a strong distortion of the PO 4 and FeO 6 polyhedra, and a significantly positive reaction free energy, making it the most resistant to proton intercalation.…”

Section: Common Drawbacks Of Chemical Redox Methods For Intercalation...mentioning

confidence: 99%

A Review of Chemically Induced Intercalation and Deintercalation in Battery Materials

Odetallah

Kuß

2023

Energy Tech

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Intercalation is the fundamental process underlying lithium‐ion batteries and related technologies. While intercalation is electrochemically induced in batteries, it can also be performed with chemical redox agents. In principle, the two processes are equivalent, although there can be differences, such as rate control, side reactions, and charge transfer mechanisms. Chemically induced intercalation can be used where electrochemical methods are impractical or impossible and continues to inspire innovative applications. This chemistry is important in synthesis and pretreatment of intercalation materials, with novel impactful applications emerging that range from lithium recycling to intercalation material‐based redox flow batteries. This review summarizes the use of chemical intercalation and serves as a resource for selecting and optimizing methods specific to material and application. Covering the whole life cycle of intercalation materials: development, synthesis, use, and finally recycling, it can be expected that these reactions will continue to have great impact on the path toward efficient and cheap energy storage.

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Section: Common Drawbacks Of Chemical Redox Methods For Intercalation...mentioning

confidence: 99%

A Review of Chemically Induced Intercalation and Deintercalation in Battery Materials

Odetallah

Kuß

2023

Energy Tech

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Surface spinel and interface oxygen vacancies enhanced lithium-rich layered oxides with excellent electrochemical performances

Zhang

Chen

et al. 2022

Chemical Engineering Journal

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Photocatalytic degradation of ciprofloxacin by Gd-Co/g-C3N4 under low-power light source: Degradation pathways and mechanistic insights

Zeng,

Wu,

Luo

et al. 2024

Journal of Water Process Engineering

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Effect of chemical oxidation of spinel-type LiNi0.5Mn1.3Ti0.2O4 by soaking in HNO3, HCl and H2SO4

Cited by 6 publications

References 26 publications

A Review of Chemically Induced Intercalation and Deintercalation in Battery Materials

A Review of Chemically Induced Intercalation and Deintercalation in Battery Materials

Surface spinel and interface oxygen vacancies enhanced lithium-rich layered oxides with excellent electrochemical performances

Photocatalytic degradation of ciprofloxacin by Gd-Co/g-C3N4 under low-power light source: Degradation pathways and mechanistic insights

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