Generation of Oxazolidine-2,4-diones Bearing Sulfur-Substituted Quaternary Carbon Atoms by Oxothiolation/Cyclization of Ynamides. -A novel method for the metal-free oxothiolation of ynamides to construct oxazolidine-2,4-diones bearing sulfur-substituted quaternary carbon atoms is developed. Title compounds are obtained in good yields and with good chemoselectivity under mild conditions. It represents a rare C-O bond cleavage of ynamides, as well as a facile approach for the formation of C-O, C-S, and C-Cl bonds. - (HUANG, H.; FAN, J.; HE, G.; YANG, Z.; JIN, X.; LIU, Q.; ZHU*, H.; Chem. -Eur.