Effect of deuteration on the ferroelectric transition temperature and the distribution coefficient of deuterium in K(H1−<i>x</i>D<i>x</i>)2PO4

Loiacono, G. M.; Balascio, J.F.; Osborne, W.N.

doi:10.1063/1.1655009

Cited by 93 publications

(48 citation statements)

References 5 publications

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“…A thorough investigation [214,215] of the deuteration dependence of the phase transition temperature for a large number of samples of K(H 1−x D x ) 2 PO 4 has confirmed the non-linear character of T c (x). Comparing the data of [214,215] with other measurements of T c (x) we can note that the values of T c (x) [214,215] agree with the data of [216,225] at 0 x 0.4 and of [226] at 0 x 0.3. Some values of T c given in [199] at x = 0.35; 0.68 and in [225] at x=0.4 coincide with the values of [214,215].…”

Section: Comparison Of the Calculated Physical Characteristics Of Thesupporting

confidence: 74%

“…Comparing the data of [214,215] with other measurements of T c (x) we can note that the values of T c (x) [214,215] agree with the data of [216,225] at 0 x 0.4 and of [226] at 0 x 0.3. Some values of T c given in [199] at x = 0.35; 0.68 and in [225] at x=0.4 coincide with the values of [214,215]. Overall, however, the values of T c (x) obtained in [199,[224][225][226] are by 5-10 K higher than those of [214,215].…”

Section: Comparison Of the Calculated Physical Characteristics Of Thesupporting

confidence: 74%

“…Some values of T c given in [199] at x = 0.35; 0.68 and in [225] at x=0.4 coincide with the values of [214,215]. Overall, however, the values of T c (x) obtained in [199,[224][225][226] are by 5-10 K higher than those of [214,215]. A rather large spread of the data is caused, most likely, by imprecise determination of the deuterium concentration in the samples of K(H 1−x D x ) 2 PO 4 .…”

Section: Comparison Of the Calculated Physical Characteristics Of Thementioning

confidence: 99%

“…In some papers [199,224,225] the dependence of the phase transition temperature in the K(H 1−x D x ) 2 PO 4 crystals on x is considered to be linear and is described by the empirical relation T c = 123 + 106x ± 2 [199], T c = 121.7 + 107x [225]. In these papers too few concentrations are usually taken into account, and T c is measured with insufficient precision.…”

Section: Comparison Of the Calculated Physical Characteristics Of Thementioning

confidence: 99%

See 3 more Smart Citations

Thermodynamics and dynamical properties of the KH_{2}PO_{4} type ferroelectric compounds. A unified model

Levitskii¹,

Zachek²,

Vdovych³

et al. 2009

Condens. Matter Phys.

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Within the framework of the proposed unified proton ordering model for the ferroelectric compounds of the KH 2 PO 4 family, in the four-particle cluster approximation for the short-range interactions and mean field approximation for the long-range interactions, we calculate thermodynamic and longitudinal dynamic characteristics of the KD 2 PO 4 type ferroelectrics and ND 4 D 2 PO 4 type antiferroelectrics. Calculations for partially deuterated K(H 1−x Dx) 2 PO 4 type ferroelectrics and N(H 1−x Dx) 4 (H 1−x Dx) 2 PO 4 type antiferroelectrics are performed within the mean crystal approximation. It is shown that at the proper choice of the theory parameters, a good quantitative description of experimental data for the KH 2 PO 4 family crystals is obtained.

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Section: Comparison Of the Calculated Physical Characteristics Of Thesupporting

confidence: 74%

Section: Comparison Of the Calculated Physical Characteristics Of Thesupporting

confidence: 74%

Section: Comparison Of the Calculated Physical Characteristics Of Thementioning

confidence: 99%

Section: Comparison Of the Calculated Physical Characteristics Of Thementioning

confidence: 99%

See 2 more Smart Citations

Thermodynamics and dynamical properties of the KH_{2}PO_{4} type ferroelectric compounds. A unified model

Levitskii¹,

Zachek²,

Vdovych³

et al. 2009

Condens. Matter Phys.

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“…Two sets of model parameters (set 2 and 3 in table 1) for KD 2 PO 4 crystal were obtained in the work [18]. However, the value 228K [24] was taken as an experimental value of the phase transition temperature which, as work [21] shows, turns out to be erroneous. …”

Section: Model Theory Parameters For Kd 2 Po 4 Crystal and Thermodynamentioning

confidence: 99%

Theoretical investigations of thermodynamic properties of partially deuterated K(H_{1-x}D_{x})_{2}PO_{4} ferroelectrics

Levitskii¹,

Lisnii²,

Andrusyk³

2007

Condens. Matter Phys.

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The research of thermodynamic properties of partially deuterated K(H 1−x Dx) 2 PO 4 crystals was performed within the framework of proton ordering model with tunnelling within the four-particle cluster approximation for short-range interaction and within the molecular field approximation for long-range interaction. The KD 2 PO 4 's model parameters were derived for the case of acceptable description of the experimental data for crystal thermodynamic characteristics. Based on the introduced procedure of deriving parameters for K(H 1−x Dx) 2 PO 4 crystals, the thermodynamic and dielectric properties of these crystals were calculated and the results were compared with the experimental ones. The problem of applying the mean crystal approximation to the analysis of physical characteristics of K(H 1−x Dx) 2 PO 4 crystals was discussed.

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Growth, structural and optical properties of 12%‐deuterated KDP crystals

Liu

Wang

et al. 2013

Crystal Research and Technology

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Key words 12%-DKDP, wideband second-harmonic generation, Raman shift, damage threshold, deuterium content.K(D 0.12 H 0.88 ) 2 PO 4 crystals were chosen to be used for quadratic nonlinear medium of wideband frequency doubling at 1 μm. A key limitation on this application is that little information can be found in the previous reports. In this work, growth as well as structural and optical properties of this crystal were investigated in detail. Experimental results in comparison with KDP indicate that lattice parameter along a-axis changes much more than lattice parameter c and infra-red absorption edge shift by 0.08 μm accompanied with increasing of transmittance in the whole region. With the introduction of deuterium atom, peak of ν 1 (PO4) shifts to lower wave number and transverse stimulated Raman scattering was effectively suppressed. Extra-ordinary and ordinary indices were also measured as function of wavelength. Good crystalline perfection and great performance of damage threshold also indicate that 12%-DKDP is an appropriate choice in the application of wideband frequency doubling at 1 μm.

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Effect of deuteration on the ferroelectric transition temperature and the distribution coefficient of deuterium in K(H1−xDx)2PO4

Cited by 93 publications

References 5 publications

Thermodynamics and dynamical properties of the KH_{2}PO_{4} type ferroelectric compounds. A unified model

Thermodynamics and dynamical properties of the KH_{2}PO_{4} type ferroelectric compounds. A unified model

Theoretical investigations of thermodynamic properties of partially deuterated K(H_{1-x}D_{x})_{2}PO_{4} ferroelectrics

Growth, structural and optical properties of 12%‐deuterated KDP crystals

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