2010
DOI: 10.5006/1.3462907
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Effect of Different Curing Agents on Cure Reaction and Exposure Resistance of Phenolic-Epoxy Resins in Hot Acid Solutions

Abstract: Linear phenolic-epoxy polymers were cured with diaminodiphenyl sulfone (DDS), metaphenylene diamine (m-DPA), and phenolic aldehyde amine (PAA), respectively, to prepare several anti-corrosion materials that are coating components. The effect of different curing agents on energy of activation (E a ) and glass transition temperature (T g ) of polymers was investigated using differential scanning calorimetry (DSC). E a of phenolic-epoxy/DDS is higher than that of phenolic-epoxy/ PAA, and lower than that of phenol… Show more

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Cited by 10 publications
(7 citation statements)
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“…be found on the polymer surface. This indicates that cross-linking network of hybrid polymer composite is not destroyed when exposed to the corrosive condition of desulfurization chimney [13] [14].…”
Section: Analysis Methodsmentioning
confidence: 99%
“…be found on the polymer surface. This indicates that cross-linking network of hybrid polymer composite is not destroyed when exposed to the corrosive condition of desulfurization chimney [13] [14].…”
Section: Analysis Methodsmentioning
confidence: 99%
“…There are not the eroded cracks or craters on the surface of hybrid composite in Figure 5(a), which demonstrates that hybrid composite has strong anti-corrosion performance. Apparently, hybrid composite has a better barrier effect than vinyl ester flake mastic [12,13].…”
Section: Morphological Observation During Corrosion Testmentioning
confidence: 98%
“…Increasing the cross-linking density of a thermoset resin typically leads to an increased solvent resistance, chemical resistance, and T g , with reduced permeation speeds [5,13,15,26,28,78,87,88]. The cross-linking density is dened as the number of moles of elastically eective network chains per sample volume or weight.…”
Section: Cross-linking Density and Crystallinitymentioning
confidence: 99%
“…Increased rigidity and reduced free volume limits the diusion rate of molecules through a coating lm. Drawings based on[87,90].…”
mentioning
confidence: 99%