Effect of different ratios of polyaniline:poly(styrene sulfonate) on the hole extraction ability in perovskite solar cells

Abdelmagid, Ahmed M.; Tahan, Ayman El; Habib, M.; Anas, M.; Soliman, Moataz

doi:10.1016/j.synthmet.2019.116232

Cited by 17 publications

(14 citation statements)

References 35 publications

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“…This shift is slightly larger due to the inclusion of Cl ion into the crystal lattice of MAPbI 3 . The appearance of series of new diffraction peaks are in good agreement with literature on the tetragonal phase of the perovskite [44]. Furthermore, the figure shows that same Pbl 2 in the MAPbI 3-x Cl x precursor appears at 12.9° (003) and 38.9° (009) and this unreacted PbI 2 passivates grain boundaries which generally worked as recombination centers.…”

Section: Figure (5) Xrd Patterns Of A)mapbi 3 and B) Mapbi 3-x CL X Thin Filmsupporting

confidence: 88%

Effect of Passivation on Properties and Performance of Perovskite Solar Cells

2020

Egyptian Journal of Solids

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Perovskite solar cells (PSCs) represent one of the most models of the organic-inorganic solar cells which have achieved a great success in the last years. However, there are some of challenges facing this success such the barrier between the layers' interfaces and the presence of grains that impedes the passage of the charge carriers. Consequently, the aim of this work is to synthesize and characterize passivated peroviskte layers using different passivation techniques for producing treated perovskite solar cells. These treated layers were characterized by scanning electron microscope (SEM), UV-visible spectroscopy, photoluminescence, X-ray diffraction (XRD), Fourier transform infrared (FTIR) and current densityvoltage measurements. The optimal performance of the fabricated and passivated PSCs with a structure of FTO/blocking layer/mesoporous layer /TiCl 4 /methylamonium (MA)PbI 3-x Cl x /chlorobenzene/C had short circuit current density (Jsc), open circuit voltage (Voc), fill factor (FF) and efficiency of 20 mA/cm 2 , 0.56 V, 0.29 and 6.5 %, respectively.

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Section: Figure (5) Xrd Patterns Of A)mapbi 3 and B) Mapbi 3-x CL X Thin Filmsupporting

confidence: 88%

Effect of Passivation on Properties and Performance of Perovskite Solar Cells

2020

Egyptian Journal of Solids

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“…planar perovskite solar cells appropriate to low-temperature processing and solution preparation have displayed superiority over conventional mesoporous counterparts, albeit with unsatisfactory PCEs. [4][5][6][7] To solve this problem, multiple attempts related to perovskite material formulations, device fabrication techniques, and interface engineering have been carried out. [8][9][10][11] In particular, the effect of the hole-transporting interface between the perovskite absorber and indium-tin oxide (ITO) electrode cannot be underestimated, which influences the energy level alignment, charge extraction, and the growth of perovskite crystals.…”

Section: Doi: 101002/adsu202100107mentioning

confidence: 99%

Tris(pentafluorophenyl)borane‐Modified P3CT‐K as an Efficient Hole‐Transport Layer for Inverted Planar MAPbI₃ Perovskite Solar Cells

You

Liu

Wang

et al. 2021

Advanced Sustainable Systems

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Polythiophene‐acid‐based conjugated polyelectrolytes have shown great potential as hole‐transport materials for the fabrication of inverted planar perovskite devices with decent power conversion efficiencies (PCEs), benefiting from their tunable structure and functional properties. In contrast to the current progress mainly from side functional group modification, here a simple and effective strategy is reported to effectively regulate the aggregation of P3CT‐K through the modification of the thiophene units in the main chain. A small molecule tris(pentafluorophenyl)borane (TPB) is applied as the Lewis acid to interact with the thiophene unit of polythiophene chain and regulate the aggregation of conjugated polyelectrolytes. The control of aggregation of P3CT‐K not only elevates the hole mobility of P3CT‐K, but also suppresses charge recombination in P3CT‐K composite films. Consequently, the high efficiency of inverted MAPbI3 perovskite solar cells is achieved with a peak power conversion efficiency of 20.7% and simultaneously improved short‐circuit current density and fill factor. This work provides an effective method for the aggregation control of the polyelectrolyte hole materials to promote the performance of inverted planar perovskite solar cells.

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“…Recently, various organic polymer semiconductors such as poly (3,4-ethylenedioxythiophene): polystyrene sulfonate, polyaniline: polystyrene sulfonate (PANI:PSS), polyaniline: camphorsulfonic acid, doped polypyrrole have been widely used as the interlayer of various organic electronic devices to improve the interaction between their transparent electrode and active material due to their easy processability, good mechanical stability, high conductivity, and environmental stability. [21][22][23][24][25][26][27][28][29][30][31][32][33] PANI:PSS has recently exhibited very good performance as a hole transport material of OPV. 22,23 It has shown a less etching effect onto the TCO electrode of the OPV owing to its lower acidity.…”

Section: Introductionmentioning

confidence: 99%

“…Further improvement of mechanical stability is crucial, and various techniques have been tried to improve the mechanical reliability of IZTO film. Recently, various organic polymer semiconductors such as poly(3,4‐ethylenedioxythiophene):polystyrene sulfonate, polyaniline: polystyrene sulfonate (PANI:PSS), polyaniline: camphorsulfonic acid, doped polypyrrole have been widely used as the interlayer of various organic electronic devices to improve the interaction between their transparent electrode and active material due to their easy processability, good mechanical stability, high conductivity, and environmental stability 21–33 . PANI:PSS has recently exhibited very good performance as a hole transport material of OPV 22,23 .…”

Section: Introductionmentioning

confidence: 99%

Improved mechanical stability of indium zinc tin oxide based flexible transparent electrode through interlayer treatment

Biswas

Lee

Jang

et al. 2022

J of Applied Polymer Sci

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Due to the significant growth of the market for numerous flexible electronic devices, demand for mechanically stable indium zinc tin oxide (IZTO) based flexible transparent electrodes has recently expanded substantially. So, we have attempted to increase the mechanical stability of an IZTO based flexible transparent electrode by forming an ultrathin interlayer of an organic semiconductor polystyrene sulfonate doped polyaniline (PANI:PSS). According to the results of the systematic investigation, the PANI:PSS treated IZTO film can preserve 97.50% of its initial average transmittance (AVT) value (83.07%) after 20,000 bending cycles, but the bare IZTO film can retain only 89.00% of its initial AVT value (86.40%) after the same treatment. Furthermore, the PANI:PSS treatment has benefited in the reduction of IZTO film sheet resistance from 17.38 to 16.91 Ω/sq. Scanning electron microscopy images have indicated that the presence of a PANI:PSS interlayer on the IZTO film prevents the formation of fractures on the inorganic IZTO layer when mechanical stress is applied.

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Effect of different ratios of polyaniline:poly(styrene sulfonate) on the hole extraction ability in perovskite solar cells

Cited by 17 publications

References 35 publications

Effect of Passivation on Properties and Performance of Perovskite Solar Cells

Effect of Passivation on Properties and Performance of Perovskite Solar Cells

Tris(pentafluorophenyl)borane‐Modified P3CT‐K as an Efficient Hole‐Transport Layer for Inverted Planar MAPbI₃ Perovskite Solar Cells

Improved mechanical stability of indium zinc tin oxide based flexible transparent electrode through interlayer treatment

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Effect of different ratios of polyaniline:poly(styrene sulfonate) on the hole extraction ability in perovskite solar cells

Cited by 17 publications

References 35 publications

Effect of Passivation on Properties and Performance of Perovskite Solar Cells

Effect of Passivation on Properties and Performance of Perovskite Solar Cells

Tris(pentafluorophenyl)borane‐Modified P3CT‐K as an Efficient Hole‐Transport Layer for Inverted Planar MAPbI3 Perovskite Solar Cells

Improved mechanical stability of indium zinc tin oxide based flexible transparent electrode through interlayer treatment

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Tris(pentafluorophenyl)borane‐Modified P3CT‐K as an Efficient Hole‐Transport Layer for Inverted Planar MAPbI₃ Perovskite Solar Cells