Effect of diluents on the extraction and separation of Fe(III) and Cu(II) from hydrochloric acid solutions using N,N,N′,N′-tetrabutyl succinamide

Ligand structure and diluent nature in defining improved Am3+ and Cm3+ separation using diglycolamides: a combined solvent extraction and DFT study

“…Organic diluents play a significant role in controlling the extraction behavior of the metal ions. 36,37 It is, therefore, of interest to evaluate different diluents for the extraction of Am 3+ and Cm 3+ with the DGA derivatives in the presence of SO 3 PhBTP in the aqueous phase. Besides the common aliphatic hydrocarbon, n -dodecane, a series of aromatic hydrocarbon solvents was chosen as the organic diluents for the Am 3+ /Cm 3+ separation study.…”

Remarkable Improvement in Am3+ and Cm3+ Separation Using a Cooperative Counter Selectivity Strategy by a Combination of Branched Diglycolamides and Hydrophilic Polyaza-heterocycles

“…Organic diluents have a significant effect on the extraction behavior of metal ions. 40,41 A number of organic diluents of varying polarity were chosen to study the Am 3+ and Cm 3+ separation from a 0.2 M HNO 3 medium containing 1 mM SO 3 PhBTPhen (Figure S1). TODGA and T2EHDGA were chosen as representative DGA derivatives for the diluent variation studies because of their higher solubility in a wide range of organic diluents as compared to other DGA derivatives having shorter alkyl chains.…”

“…Organic diluents have a significant effect on the extraction behavior of metal ions. , A number of organic diluents of varying polarity were chosen to study the Am 3+ and Cm 3+ separation from a 0.2 M HNO 3 medium containing 1 mM SO 3 PhBTPhen (Figure S1). TODGA and T2EHDGA were chosen as representative DGA derivatives for the diluent variation studies because of their higher solubility in a wide range of organic diluents as compared to other DGA derivatives having shorter alkyl chains. , In our previous report, we observed that among the three aromatic hydrocarbon diluents toluene, t Bu-benzene, and tri iso -propylbenzene, the highest selectivity was observed in the case of toluene, and therefore, in this study, toluene was chosen.…”

Solvent Extraction of Iron(III) from Al Chloride Solution of Bauxite HCl Leaching by Mixture of Aliphatic Alcohol and Ketone

“…Cui et al [16,17] studied the extraction of iron(III) from HCl by extractants N,N,N′,N′tetrabutylmalonamide (TBMA) and N,N,N′,N′-tetrabutyl-3β-hydroxyglutaramide (TBDGA). The extraction results were compared with those of N,N,N′,N′tetrabutylsuccinamide (TBSA) to understand the relationship between the chemical structure of the extractants and the iron(III) extraction degree.…”