Effect of external electric fields on sulfur dioxide–water systems

Wu, Shiyue; Yang, Xiaoqing; Jing, Heng; Chu, Yong; Yuan, Jianping; Zhu, Zhanxia; Huang, Keh‐Ning

doi:10.1016/j.molliq.2022.119023

Journal of Molecular Liquids

2022

DOI: 10.1016/j.molliq.2022.119023

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Effect of external electric fields on sulfur dioxide–water systems

Shiyue Wu

Xiaoqing Yang

Heng Jing

et al.

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2024

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Cited by 2 publications

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“…Since then, the chem-and regio-selectivity of Diels-Alder reaction catalyzed by OEEF were also verified not only by theorical calculations but also experimental study [50,51]. Now, OEEF is also used to explore the physical properties of the cluster B 12 C 4 N 8 , the effects of the environmental pollution source-sulfur dioxide and bromobenzene, and so on [52][53][54]. As for the N 2 O molecule, the investigations revealed that the N O bond length and its total energy are influenced by OEEF [55].…”

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confidence: 99%

Deoxygenation reactions of nitrous oxide assisted by oriented external electric field

Zhang,

Li,

Lei

et al. 2024

Int J of Quantum Chemistry

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Due largely to the high stability and the potential ozone‐depleting, the transformation of greenhouse gas nitrous oxide has gained much attentions. In present paper, a new insight into the deoxygenation of nitrous oxide with silane was reported by using oriented external electric field (OEEF) as a catalytic strategy. When the OEEF was employed, the reaction barrier of deoxygenation was marvelously decreased as it was oriented along the positive NO/OSi bond‐axis. Especially the field strength is 300 × 10−4 a.u., the differences are up to 22.4/18.3 kcal mol−1 as compared with that of nonfield. In addition, once the H atom in SiH4 was replaced by methyl, two reaction modes were obtained, in which the deoxygenation process was easier when the N2O captured the H atom attached to the Si atom, not attached to the C atom. Further, the solvent effects of deoxygenation reaction were also considered, but with a weak influence were obtained.

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confidence: 99%

Deoxygenation reactions of nitrous oxide assisted by oriented external electric field

Zhang,

Li,

Lei

et al. 2024

Int J of Quantum Chemistry

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Electrically enhanced adsorption performance of functionalized aluminum-nitride nanotubes for removal of sulfate ions in water

Chang,

Han,

et al. 2024

Journal of Molecular Liquids

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Effect of external electric fields on sulfur dioxide–water systems

Cited by 2 publications

References 58 publications

Deoxygenation reactions of nitrous oxide assisted by oriented external electric field

Deoxygenation reactions of nitrous oxide assisted by oriented external electric field

Electrically enhanced adsorption performance of functionalized aluminum-nitride nanotubes for removal of sulfate ions in water

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