Flue gas recirculation (FGR) is a method used in several
industries
to control emissions and process conditions, such as NO
x
reduction and temperature levels, and increase the
CO2 concentration in the off-gas, to be better suited for
methods of carbon capture. In this study, the influence of FGR, varying
levels of flue gas flow and oxygen concentration on the emissions
of polycyclic aromatic hydrocarbons (PAHs) was investigated during
Si alloy production. In addition, computational fluid dynamics (CFD)
modeling was performed using OpenFOAM for combustion of C2H2 and H2 with varying O2 levels
to simulate FGR and to gain better insight into the impact of furnace
operations on the PAH evolution. Experimental results show that increasing
FGR (0–82.5%) and decreasing levels of oxygen (20.7–13.3
vol %) increase the PAH-42 concentration from 14.1 to 559.7 μg/Nm3. This is supported by the simulations, where increased formation
of all PAHs species was observed at high levels of FGR, especially
for the lighter aromatic species (like benzene and naphthalene), due
to the lower availability of oxygen and the reduction in temperature.
Residence time was identified as another key parameter to promote
complete combustion of PAHs. Benzene oxidation can be prevented with
temperatures lower than 1000 K and residence times smaller than 1
s, while complete oxidation is found at temperatures of around 1500
K.