Effect of Graphene Oxide Concentration in Electrolyte on Corrosion Behavior of Electrodeposited Zn–Electrochemical Reduction Graphene Composite Coatings

Yang, Bin; Zhang, Pengfei; Wang, Guangxin; Wang, Aiqin; Chen, Xiaofang; Wei, Shizhong; Xie, Jingpei

doi:10.3390/coatings9110758

Cited by 14 publications

(3 citation statements)

References 38 publications

(49 reference statements)

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“…In this case magnetic iron oxide nanoparticles were coupled with GO and a magnetic field was then employed to give GO nanosheets parallel to the surface. In addition, efficient anti-corrosion coatings have been formulated using electroplated Zn/GO nanocomposite coatings [186] and low-pressure cold-sprayed coatings [187]. For example, Li et al [188] and Moshgi Asl et al [189] used pulsed electrodeposition while galvanostatic deposition [190] has also been employed to form Zn/GO composites with high stability and good corrosion protection performance.…”

Section: Graphene Modified Zinc Rich Coatingsmentioning

confidence: 99%

Review of Recent Developments in the Formulation of Graphene-Based Coatings for the Corrosion Protection of Metals and Alloys

Healy

Tian

Alves

et al. 2020

CMD

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Corrosion is a naturally occurring phenomenon and there is continuous interest in the development of new and more protective coatings or films that can be employed to prevent or minimise corrosion. In this review the corrosion protection afforded by two-dimensional graphene is described and discussed. Following a short introduction to corrosion, the application of graphene in the formulation of coatings and films is introduced. Initially, reduced graphene oxide (rGO) and metallic like graphene layers are reviewed, highlighting the issues with galvanic corrosion. Then the more successful graphene oxide (GO), functionalised GO and polymer grafted GO-modified coatings are introduced, where the functionalisation and grafting are tailored to optimise dispersion of graphene fillers. This is followed by rGO coupled with zinc rich coatings or conducting polymers, GO combined with sol-gels, layered double hydroxides or metal organic frameworks as protective coatings, where again the dispersion of the graphene sheets becomes important in the design of protective coatings. The role of graphene in the photocathodic protection of metals and alloys is briefly introduced, while graphene-like emerging materials, such as hexagonal boron nitride, h-BN, and graphitic carbon nitride, g-C3N4, are then highlighted.

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Section: Graphene Modified Zinc Rich Coatingsmentioning

confidence: 99%

Review of Recent Developments in the Formulation of Graphene-Based Coatings for the Corrosion Protection of Metals and Alloys

Healy

Tian

Alves

et al. 2020

CMD

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“…Composite coatings with excellent properties can be obtained owing to the dispersion strengthening and pinning effect between different nanoparticles [13]. In the present study, a single nanoparticle composite coating was prepared using a surface treatment technology, and the results were compared with those of a pure substrate [14]. The composite synergy effect of multiple nanoparticles has rarely been studied, with even fewer studies on the effects of current density on the performance of composite coatings with multiple nanoparticles.…”

Section: Introductionmentioning

confidence: 99%

Effect of Current Density on the Performance of Ni–P–ZrO2–CeO2 Composite Coatings Prepared by Jet-Electrodeposition

Song

Zhang

et al. 2020

Coatings

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The objective of this study was to improve the surface properties, hardness, wear resistance and electrochemical corrosion resistance of #45 steel. To this end, Ni–P–ZrO2–CeO2 composite coatings were prepared on the surface of #45 steel using the jet-electrodeposition technique by varying the current density from 20 to 60 A/dm2. The effect of current density on the performance of the composite coatings was evaluated. Scanning electron microscopy (SEM), energy dispersive X-ray spectroscopy (EDS) and X-ray diffraction (XRD) were applied to explore the surface topography, elemental composition, hardness and electrochemical corrosion resistance of the composite coatings. The results showed that with the increase in the current density, the hardness, wear resistance, and electrochemical corrosion resistance tends to increase first and then decrease. At a current density of 40 A/dm2, the hardness reached a maximum of 688.9 HV0.1, the corrosion current reached a minimum of 8.2501 × 10−5 A·cm−2, and the corrosion potential reached a maximum of −0.45957 V. At these values, the performance of the composite coatings was optimal.

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“…[41][42][43] Ghulam et al 24 fabricated the nickel/graphene composite coatings with improved mechanical and anticorrosive properties by increasing the concentration of SDS appropriately. Bin et al 44 optimized the GOs concentration in the electroplating solution under the assistance of CTAB surfactant and prepared the zinc/GOs composite coating with enhanced corrosion resistance.…”

mentioning

confidence: 99%

Electrodeposition of Nickel/Graphene Oxide Particle Composite Coatings: Effect of Surfactants on Graphene Oxide Dispersion and Coating Performance

Zhang

2020

J. Electrochem. Soc.

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The dispersibility of graphene oxide particles (GOs) in nickel electrolytes is critical for its uniform incorporation in the nickel matrix during the electrodeposition process. In this study, we study the fundamental interaction of surfactants and nickel ionic strength for uniform and stable incorporation of GOs in nickel electrolytes and their effect on coating performance. The results indicate that the non-ionic surfactant Polyethylene glycol (PEG) has the optimal dispersibility of GOs in nickel electrolyte, followed by the cationic surfactant Cetyltrimethylammonium bromide (CTAB) and the anionic surfactant Sodium dodecyl sulfate (SDS). It is also noted that the increasing nickel ionic strength would deteriorate the stability of GOs, attributing to the generation of cross-linking of high strength divalent nickel ions with dispersed graphene oxide. The electrodeposited coatings show that more incorporation of graphene oxide in the coating is achieved when the PEG surfactant is used, which leads to an increased hardness by 146% and a decreased friction coefficient by 72.7% under low nickel sulfamate concentration (200 g l−1), compared to pure nickel coating. Eventually, the study shows that higher nickel ionic strength would deteriorate the performance of the coatings, while the selection of proper surfactant can compensate for it.

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Effect of Graphene Oxide Concentration in Electrolyte on Corrosion Behavior of Electrodeposited Zn–Electrochemical Reduction Graphene Composite Coatings

Cited by 14 publications

References 38 publications

Review of Recent Developments in the Formulation of Graphene-Based Coatings for the Corrosion Protection of Metals and Alloys

Review of Recent Developments in the Formulation of Graphene-Based Coatings for the Corrosion Protection of Metals and Alloys

Effect of Current Density on the Performance of Ni–P–ZrO2–CeO2 Composite Coatings Prepared by Jet-Electrodeposition

Electrodeposition of Nickel/Graphene Oxide Particle Composite Coatings: Effect of Surfactants on Graphene Oxide Dispersion and Coating Performance

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