Highlights:(1) Graphene Oxide (GO) caused a significant reduction in fluidity and a slight decrease in compressive strength of AAS mortars.(2) The flexural strength of hardened mortars were improved by adding GO.(3) Layered double hydroxides (LDHs) were observed and confirmed in GO-added AAS system.
AbstractDue to its high aspect ratio and outstanding tensile strength, graphene oxide (GO) can dramatically reduce the brittleness of cement-based materials. In this paper, GO nanosheets were successfully synthesised using the modified Hummers' method. Effects of the GO on the fluidity, mechanical properties of alkali-activated slag (AAS) mortars and the microstructure of the AAS pastes were studied.It is found that addition of the GO caused a significant reduction in fluidity and a slight decrease in the compressive strength of the hardened mortars. However, the GO improved the flexural strengths by 20% with a dosage of 0.01 wt. % after 7 days. Large-scale layered double hydroxides (LDHs) were observed using SEM, the compositions of which were identified and EDS and XRD. A possible mechanism of the formation of LDHs in the GO-AAS system is proposed. Due to the Mg 2+ /Al 3+ decomposed from the slag and the Al(OH)4 -formed in the high pH condition in the GO-AAS system, the reaction pathway of LDHs 2 can be regarded as a , This research provides a further understanding of the effect of graphene oxide which has a potential application of GO in AASC.