Severe Canadian winter conditions and growing traffic volumes are vital factors resulting in a reduction of the service life of flexible pavements. Researchers and engineers strived to develop several additives to develop balanced asphalt mixers capable of resisting distresses that caused deterioration of flexible pavements in Canada. In this study, a critical literature review regarding the use of geopolymers and their application in construction materials is provided. Moreover, an experimental matrix of laboratory testing was conducted to study the rheological and microstructural properties of the PG 58-28 asphalt binder, with different percentages (0%, 3%, 6%, and 9%) of geopolymer. The effect of geopolymer-curing time on rheological properties was investigated. Rotational viscometer, dynamic shear rheometer (DSR), and environmental scanning electron microscopy (ESEM) imaging devices were used to compare the performance of control binder with a binder with different percentages of geopolymers. Results indicated that the increase in the geopolymer content and the curing time affect the rheological behavior of the asphalt binder by increasing its viscosity, complex shear modulus, and failure temperature. Samples with higher geopolymer percentage exhibited better performance in terms of rutting resistance. Moreover, an increase in the failure temperature of modified asphalt binder with 9% geopolymer is recorded as 8.58%, 14.2%, and 15.2% for curing times of 2, 7, and 14 days, respectively, compared with virgin asphalt. Furthermore, the nanoparticles appear to be well dispersed in the binder, and increasing the percentage of the geopolymer does not seem to affect the microstructure of the binder. Overall research conclusion is that geopolymer application resulted in a potential enhancement of some of the properties of the asphalt binder.