“…Accordingly, when high pressures (600 MPa) are applied to the packaging material with different food simulants, the ε-caprolactam migration phenomenon is inferior when compared with conventional thermal processing (0.1 MPa/90 • C/10 min). According to Guillard, Mauricio-Iglesias, and Gontard (2010), Song (2014) and Ayvaz, Balasubramaniam, and Koutchma (2016), during high pressure compression, the polymer matrix loses its ability to interact with food due to the reduction of free volume. As the pressure is released, the polymer gradually recovers its original state and, therefore, migration processes can occur as expected at normal atmospheric pressure, which may explain the results of our study.…”