Effect of hybrid sizings on the surface morphology, mechanical behavior of basalt fibers, and fiber/epoxy composite properties

Abstract

In the present study, the basalt fibers (BFs) were treated with hybrid sizings consisting silane coupling agent (3‐Glycidoxypropyl)trimethoxysilane, and silicon dioxide nanoparticles (SNPs). Using acetone washing and heat treatment, the commercial sizing previously on the BFs was removed. Next, the fibers were dip‐coated, and silanes condensed on the surface of the fibers. Fiber samples were characterized using thermogravimetric analysis (TGA), atomic force microscopy (AFM), X‐ray photoelectron spectroscopy (XPS), and scanning electron microscopy (SEM). The test findings demonstrate that acetone extraction was an effective way to remove sizings. The AFM analysis and SEM micrographs demonstrate that SNP and silane particles were dispersed uniformly across the fiber surface. The single fiber tensile testing results indicated that the deposition of hybrid sizings enhanced the fibers strength. Because of the better adhesion between the fiber and epoxy, the hybrid sizings also improved the flexural strength by 22.28% and the interlaminar shear strength by 20.75%.Highlights Hybrid sizings (silanes and nano‐particles) on the basalt fiber surface. Characterization of the sizings and understanding of surface morphology. Hybrid sizings resulted in better tensile strength. Failure mechanisms of the fibers were observed using fractography. The effect of hybrid sizing on ILSS and flexural properties was observed.