Effect of Hydrogen on the Iron- and Nickel-Catalyzed Formation of Carbon from Benzene

LaCava, A.I.; Fernandez-Raone, E. Daniel; Isaacs, L. L.; Caraballo, Maritza

doi:10.1021/bk-1983-0202.ch005

Cited by 4 publications

(5 citation statements)

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“…This has also been observed for coke formation results on nickel [58,59,[62][63][64][66][67][68][69][70][71][72][73][74][75][76][77]. Also the film formation of GaAs has been shown to decrease with increasing temperature starting as low as 600°C by various authors [78][79][80][81][82].…”

Section: Tga Vapor Deposition Proceduressupporting

confidence: 63%

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Vapor phase deposition studies of phosphate esters on metal and ceramic surfaces

Deckman¹,

Hsu²,

Klaus³

1988

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of the DOE ECUT Tribology Program have at the same time sponsored a major Tribology program at NBS. That program also benefited from the studies conducted by Mr. Gates, Mr. Yellets, and Mr. Deckman. These students, while not working on sponsored projects directly, enabled NBS to explore some high risk, high pay off projects parallel to ECUT projects. When appropriate, the students were supported by ECUT for some time. To this, we gratefully acknowledge the generous support of DOE ECUT, without whose support many ideas would not be explored.

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Section: Tga Vapor Deposition Proceduressupporting

confidence: 63%

“…The amount of coke produced on iron surfaces decreases in the following order FeO > Fe~Fe 2 0 3 > Fe 3 C[61]. While iron produced substantial quantities of coke, LaCava et al[62] determined nickel forms even more. And a Ni-Fe surface produces more coke than either of the parent materials[63] suggesting a synergetic interaction between the two metals.…”

mentioning

confidence: 99%

Vapor phase deposition studies of phosphate esters on metal and ceramic surfaces

Deckman¹,

Hsu²,

Klaus³

1988

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“…At higher TCP vapor concentrations (figs. 19,21) it is observed that in nitrogen nickel remains non-catalytic, but in air a high deposition rate at short exposure times indicates some catalytic activity. This initial high rate is soon diminished to a non-catalytic constant rate.…”

Section: Effect Of Lubricant Vapor Concentrationmentioning

confidence: 99%

“…Several investigators have observed filamentous-tubular deposits in the formation of coke from hydrocarbons [20][21][22].…”

Section: Trimethylolpropane Triheptanoate (Tmpth)mentioning

confidence: 99%

Formation of lubricating films at elevated temperatures from the gas phase

Klaus¹,

Naidu²,

Munro³

et al. 1988

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“…As more carbon is deposited, a carbon filament is formed, carrying metal particles on top of it [8]. The carbon precipitation can give rise to structural deficiency in the carbon lattice, creating reactive carbon centers along the filament skin [9]. The hydrocarbon radicals and molecules from the gas phase are incorporated in these reactive sites, where lateral growth of the filaments occurs.…”

Section: Introductionmentioning

confidence: 99%