2023
DOI: 10.1002/poc.4582
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Effect of N, S atoms on the mechanisms of H‐transfer for five‐membered nitrogen‐containing heterocycles

Yan‐Hua Fu,
Kai Wang,
Liguo Yang
et al.

Abstract: As the mechanisms of the hydride transfer reaction between 7,8‐dihydro‐9‐methylcaffeine (CAFH) with N‐methylacridinium (AcrH+ClO4‐) and hydrogen atom transfer (HAT) reaction between 2,3‐dihydrobenzo‐imidazoles (BIH) with 2,2‐diphenyl‐1‐picrylhydrazyl radical (DPPH•) were researched to both be induced by electron transfer, the reaction mechanisms of 2,3‐dihydrobenzo‐thiazoles (BTH) with these two substrates were studied. The thermodynamic analysis platforms were used to judge the mechanisms, and the mechanisms … Show more

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