This study presents a comprehensive numerical computation of heat‐mass transfer characteristics of single‐walled carbon nanotube (SWCNT)/multi‐walled carbon nanotube (MWCNT)‐water suspension flow over a porous stretching sheet with an inclined magnetic field. The governing equations for fluid flow characteristics are formulated using the Sisko fluid model to capture the Newtonian and non‐Newtonian behavior of the nanotube‐water mixture. The nonlinear coupled partial differential equations are converted into nonlinear dimensionless coupled ordinary differential equations using suitable similarity transformations. These equations are solved using MATLAB by implementing the four‐stage Lobatto IIIa formula. The comprehensive set of computations is performed to explore the influence of pertinent parameters, including Sisko fluid parameters, concentration of nanotubes, stretching sheet velocity, and porous medium characteristics on the flow, heat, and mass transfer profiles. From the graphs and statistical analysis, it is clear that the volume fraction of SWCNT and MWCNTs are strongly correlated. The investigation reveals that increasing the inclination angle affects the fluid velocity. The variation in all flow features is negligible for volume fractions of CNTs between 0% and 10% but a significant effect is observed only beyond 10%. Higher volume fractions of CNTs result in enhanced local heat transfer coefficient. This can be attributed due to the outstanding heat transfer capabilities of CNTs owing to their high thermal conductivity. However, Shear thickening fluids exhibit high heat transfer phenomena when compared to shear‐thinning and Newtonian fluids. This research provides valuable insights into the optimization of CNT‐based nanofluids for efficient heat and mass transfer applications in electronics cooling, heat exchangers, and solar energy systems, offering opportunities to enhance energy efficiency and device performance.