2001
DOI: 10.1002/pen.10913
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Effect of interdiffusion regions on penetrant flux through multilayer films

Abstract: Barrier properties of polymer films can be improved in various ways, such as formation of multilayer structures by coextrusion, surface treatment, and coatings. This work explores the use of thousands of alternating layers of polymer (xyxy…) to modify the resistance to permeation. A model is presented to predict the number of layers needed in a laminate to change the flux of a permeant by a given amount. An important feature of the model is the species transport across the interdiffusion regions at the polymer… Show more

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Cited by 5 publications
(2 citation statements)
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“…In recent years, microlayered coextrusion with an assembly of several laminating‐multiplying elements (LMEs; it is a die that doubles the layer number of polymer material) has been developed to prepare the alternating‐layered composites consisting of layers of polar polymer with high resistance to nonpolar gas molecules [19–22]. More recently, Baer and coworkers improved the oxygen barrier property of alternating‐layered composites through adjusting the thickness of polar polymer layer and its crystallization behavior [23–26].…”
Section: Introductionmentioning
confidence: 99%
“…In recent years, microlayered coextrusion with an assembly of several laminating‐multiplying elements (LMEs; it is a die that doubles the layer number of polymer material) has been developed to prepare the alternating‐layered composites consisting of layers of polar polymer with high resistance to nonpolar gas molecules [19–22]. More recently, Baer and coworkers improved the oxygen barrier property of alternating‐layered composites through adjusting the thickness of polar polymer layer and its crystallization behavior [23–26].…”
Section: Introductionmentioning
confidence: 99%
“…In recent years, microlayered coextrusion with an assembly of several laminating-multiplying elements (LMEs; it is a die that doubles the layer number of polymer material) has been developed to prepare the alternating-layered composites consisting of layers of polar polymer with high resistance to nonpolar gas molecules [19][20][21][22]. More recently, Baer and coworkers improved the oxygen barrier property of alternating-layered composites through adjusting the thickness of polar polymer layer and its crystallization behavior [23][24][25][26].…”
Section: Introductionmentioning
confidence: 99%