“…The most typical applications of thin hard coatings include protection of cutting tools, cold and hot stamping and extrusion dies [2][3][4], due to the improvement in surface performance granted by these coatings in terms of hardness, wear and corrosion resistance properties [5][6][7][8][9][10][11][12]. Thin hard coatings can have a positive influence on the fatigue and the corrosion fatigue behavior of mechanical components, especially for relatively hard steel substrates [13][14][15][16][17][18][19][20][21][22][23]. For these reasons, PVD and CVD coatings are nowadays adopted also for other advanced applications in addition to manufacturing, including but not limited to automotive components [24][25][26][27][28], aeronautic gas engines turbine and compressor blade protection [29,30] and biomedical applications, due to the improved corrosion protection and biocompatibility granted by thin hard coatings [31].…”