Effect of irregular silicon carbide and tackifying phenolic resin on friction coefficients of rubber compounds

Abstract

Rubber compounds with high friction coefficients are widely used in safety shoes, functional shoes, etc. However, in the presence of a liquid lubrication layer, friction coefficients between rubber compounds and the opposing surface are generally very low. In this work, friction coefficients of rubber compounds are improved by a two‐pronged method. First, micron silicon carbides (SiC) with irregular shape and knife‐edge are selected as fillers to improve the plowing friction in dry state, and to improve the adhesive friction in wet state via piercing the liquid lubrication layer. Second, tackifying phenolic resin is added to increase the damping performance of rubber compounds, so as to improve the hysteresis friction in both dry and wet states. The results show that the comprehensive static and dynamic friction properties of rubber compounds are the best in both dry and wet states (0.5 wt% sodium dodecyl sulfate solution or 90 wt% glycerol solution), when SiC size is 7–14 μm and SiC content is 75–90 phr. Phenolic resin can increase the loss factor (tanδ) and loss modulus (E") of rubber compounds, and improve the static and dynamic friction coefficients in wet state (90 wt% glycerol solution). At the same time, it can improve the hardness of rubber compounds and reduce the relative content of SiC, thus reducing the static and dynamic friction coefficients of rubber compounds in dry and wet states (0.5 wt% sodium lauryl sulfate aqueous solution). In general, the optimal content of phenolic resin is 10–15 phr.Highlights Rubber friction coefficients improved via both adhesion and hysteresis friction. Irregular silicon carbides pierce liquid layer to improve adhesive friction of rubber. Phenolic resin increases hysteresis friction of rubber via damping property.