Growing awareness of sustainability in the landfill cover system has increased the use of biochar amendment for degraded landfill surface soils. Hydraulic and vegetative benefits of biochar on cover soil have been studied in the past, while ignoring mechanical characteristics, which is important to understand progressive failure of landfill infrastructure. In this study, the mechanical characteristics of four soil–biochar composites were investigated by conducting 81 unconfined compressive strength test. The results based on four in-house produced biochar were used to study the effect of compaction state (density, moisture content) and biochar percentage (5% and 10%) on unconfined compressive strength of soil–biochar. The ductility of soil–biochar was investigated for all the four biochars. Results from this study indicate a contrasting observation of strength gain depending on the type of biochar. The unconfined compressive strength of soil–biochar is potentially influenced by the different surface functional groups of biochar (hydrophilicity/hydrophobicity) and soil-biochar interlocking. It was noted that the peanut shell biochar gave comparable unconfined compressive strength of soil–biochar with that of bare soil for different compaction state. However, a diminution in the unconfined compressive strength was observed for all the other three soil–biochar sourced from water hyacinth, saw dust, and poultry litter. The study indicates that the use of biochar in soils does not ensure an improvement in the strength of soil–biochar. Enhancement in ductility was found for all the four soil–biochar irrespective of compaction state. Improvement in ductility was maximum when the soil–biochar is compacted at the dry state of optimum. Plant-based biochar has higher potency to increase the ductility of soil as compared to the animal-based biochar. Our study identifies peanut shell biochar ideal for landfill cover amendment material, considering its mechanical characteristics and design criterion. Soil biochar composite from water hyacinth, saw dust, and poultry litter can be used for potential application in green-infrastructure.