“…Knowledge of these signs is, however, vital in many applications. 4,5,6,7,8,9,10,11 For example, in the short pulse productions of wave packets, 4,5 the fluorescence signal is composed of the beatings between many transitions whose signs fundamentally affect the observations. We have previously shown 12,13,14 that given the squares of the TDMs, we are able to derive the TDMs amplitudes and perform a point-by-point construction of the excited Born−Oppenheimer potential energy surface (PES) from which the emission occurs.…”