In this paper, a recyclable and sustainable organic–inorganic
composite membrane (hereafter referred to as PPS) was synthesized
by solvent casting method using poly(vinyl alcohol) (PVA), phosphoric
acid (H3PO4), and sodium silicate (Na2SiO3) as raw materials, aiming to reduce or even replace
the use of conventional plastics. The effects of the concentrations
of H3PO4 and Na2SiO3 on
the membrane properties were investigated, and the results showed
that the PPS material has a dense structure, good thermal stability,
tensile strength up to 48.36 MPa, and elongation at break up to 520.44%.
Compared with PVA, the tensile strength and elongation at break were
increased by 1.64 and 5.79 times, respectively, and its hydrophilicity
was reduced by 27%. The strength and stability of the material were
improved through hydrogen bonding and esterification between the compounds,
and the toughness and hydrophobicity of the material were enhanced.
In addition, the disconnected composite membrane can be bonded by
wet pressing and can be recycled to recast into a membrane after dissolving
in water at 80 °C. The manufacture of PPS by solvent casting
is simple, does not produce large amounts of toxic gases in production,
is recyclable and sustainable, and meets the requirements of industrial
environmental protection.