Effect of magnesium doping on the properties and crystalline perfection of bis(thiourea)zinc(II) chloride crystals

Muthu, K.; Bhagavannarayana, G.; Meenakashisundaram, S.P.; Mojumdar, S. C.

doi:10.1007/s10973-012-2385-4

Cited by 15 publications

(1 citation statement)

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“…These dopants contribute the alterations in the linear optical, thermal strength, mechanical stability and second order harmonic generation (SHG) efficiency by their coordination modes. [18][19][20][21] Due to their increasing of hydrogen bond network between the combination of organic and metal complexes has provided the good structural properties, improved mechanical strength, thermal strength and chemical strength of crystals. [5,22,23] The good quality metal-organic NLO crystal is being achieved by modifying their structural and physicochemical properties.…”

Section: Introductionmentioning

confidence: 99%

Investigation on the Effects of MnCl₂ Doping on Structural and Optical Properties of DAST Single Crystals as Materials for Second Order Nonlinear Optics

Sivakumar

Eniya

Sundar

et al. 2021

Crystal Research and Technology

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The intent is to explore the optoelectronic properties of metal ions doped stilbazolium derivative, 4-N,N′-dimethylamino-N-methyl-4-stilbazolium tosylate (MnCl 2 -DAST) nonlinear optical crystal materials for the existing technological necessities. The Mn-DAST single crystals are crystallized by adopting the slow evaporation solution technique (SEST). The structural and crystallographic dimensions of grown crystals are affirmed using single-crystal X-ray diffraction and powder crystal X-ray diffraction. Fourier transform infrared spectra are performed to explicate the functional groups and energy dispersive X-ray analysis (EDAX) spectra confirm the presence of the chemical elements of grown crystals. The UV-vis absorption spectra of DAST and Mn-DAST crystals exhibit all possible n-* and -* electronic transitions. The blue shift is observed in the doped materials due to the exchange of lone pair electrons between the metal ions and organic molecule. Tremendously, the second order harmonic generation (SHG) efficiency of Mn (0.01 mol%) doped DAST crystals has 1.68 times larger than that of DAST crystal. From the metal-organic crystals (Mn-DAST), all the results brought out are the promising materials in the design of nonlinear optical applications.

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Section: Introductionmentioning

confidence: 99%

Investigation on the Effects of MnCl₂ Doping on Structural and Optical Properties of DAST Single Crystals as Materials for Second Order Nonlinear Optics

Sivakumar

Eniya

Sundar

et al. 2021

Crystal Research and Technology

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show abstract

Enhanced optoelectronic, thermal, mechanical and third order nonlinear optical properties of dichlorobis(thiourea)zinc(II) crystal: an effect of Phenol red dye

Ganesh

Shkir

AlFaify

et al. 2017

J Mater Sci: Mater Electron

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Synthesis, growth and investigation of structural, optical, photoluminescence and thermal studies on the ZnSO4-doped DAST crystal for NLO applications

Sivakumar

Vignesh²,

Jeyaperumal

et al. 2021

J Mater Sci: Mater Electron

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Effect of magnesium doping on the properties and crystalline perfection of bis(thiourea)zinc(II) chloride crystals

Cited by 15 publications

References 50 publications

Investigation on the Effects of MnCl₂ Doping on Structural and Optical Properties of DAST Single Crystals as Materials for Second Order Nonlinear Optics

Investigation on the Effects of MnCl₂ Doping on Structural and Optical Properties of DAST Single Crystals as Materials for Second Order Nonlinear Optics

Enhanced optoelectronic, thermal, mechanical and third order nonlinear optical properties of dichlorobis(thiourea)zinc(II) crystal: an effect of Phenol red dye

Synthesis, growth and investigation of structural, optical, photoluminescence and thermal studies on the ZnSO4-doped DAST crystal for NLO applications

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Effect of magnesium doping on the properties and crystalline perfection of bis(thiourea)zinc(II) chloride crystals

Cited by 15 publications

References 50 publications

Investigation on the Effects of MnCl2 Doping on Structural and Optical Properties of DAST Single Crystals as Materials for Second Order Nonlinear Optics

Investigation on the Effects of MnCl2 Doping on Structural and Optical Properties of DAST Single Crystals as Materials for Second Order Nonlinear Optics

Enhanced optoelectronic, thermal, mechanical and third order nonlinear optical properties of dichlorobis(thiourea)zinc(II) crystal: an effect of Phenol red dye

Synthesis, growth and investigation of structural, optical, photoluminescence and thermal studies on the ZnSO4-doped DAST crystal for NLO applications

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Product

Resources

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Investigation on the Effects of MnCl₂ Doping on Structural and Optical Properties of DAST Single Crystals as Materials for Second Order Nonlinear Optics

Investigation on the Effects of MnCl₂ Doping on Structural and Optical Properties of DAST Single Crystals as Materials for Second Order Nonlinear Optics