radiations in this process are used for the identification of the elemental composition of the sample [7][8][9].LIBS offers many advantages over other spectroscopic techniques such as mass spectroscopy, electrode spark and inductively coupled plasma. Some of LIBS unique advantages include the ability to make in situ analysis even in hostile environment, remote sensing, little or no preparation of the sample, and multi-element analysis [10][11][12]. Based on these advantages, LIBS has been extensively investigated on several samples including liquids [13], gases [14] and as well from non-conducting and conducting solids [15].LIBS is also a spectroscopic technique for the determination of the density of electron, electron temperature and number densities of the plasma plume [16,17]. Laserinduced plasma temperatures are influenced by various experimental conditions such as ambient surrounding, laser energy and laser pulse width. Most of the studies on LIBS temperatures report that the plasma temperature tends to increase with increasing laser energy, pulse width, laser wavelength and ambient pressure [18][19][20][21].Although LIBS has been employed successfully in several experimental and theoretical works, to analyze the spectroscopic composition of the samples, there are still many aspects which need to be investigated [6]. For example, Barthelemy et al. [22] investigated the influence of the laser parameters of an aluminum-induced plasma. They reported that the temperature slightly decreases at the plasma edge and close to the aluminum surface. This decrease in temperature at the plasma edge is basically caused by radiative cooling, while the decrease in temperature at the aluminum surface is as a result of thermal conduction. The authors also found that at the first microsecond of the ablation plume, the electron density was spatially homogeneous.Zhang et al.[23] also reported on the influence of laser parameters on plasma temperature. Their results predicted Abstract The magnesium plasma induced by a 1064-nm Q-switched Nd:YAG laser in atmospheric air was investigated. The evolution of the plasma was studied by acquiring spectral images at different laser energies and delay times. We observed that the intensities of the spectral lines decrease with larger delay times. The electron temperature was determined using the Boltzmann plot method. At a delay time of 100 ns and laser energy of 350 mJ, the electron temperature attained their highest value at 10164 K and then decreases slowly up to 8833.6 K at 500 ns. We found that the electron temperature of the magnesium plasma increases rapidly with increasing laser energy.