2024
DOI: 10.1002/slct.202401334
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Effect of Metal Coordination Environment on the Stability of Zinc Complexes and Their Reactivity with NaSH

Marina Lamberti,
Maria Vittoria Galotto,
Ermanno Vasca
et al.

Abstract: Metal complexes with multidentate ligands are frequently used as model compounds to shed light on the (bio)‐inorganic chemistry of H2S. Zinc complexes bearing salen‐type ONNO ligands with different bridging groups are particularly relevant in this respect. Here, we describe the use of zinc complexes with the sulfur‐analogues of the ONNO ligands with the S‐donors replacing either the neutral nitrogen donors or the anionic oxygen atoms of the classical salen ligands. In addition, we studied a hexadentate cyclic … Show more

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