“…High-energy anode materials have attracted significant attention because of high energy density, broad operating temperature range, low self-discharge rate, long cycle life, high voltage, and no voltage depression [1,2]. However, commercially-used graphite anode material has a low specific capacity, the theoretical capacity of 372mAh/g [2], currently, there are an important direction of the lithium ion battery of looking for a higher specific capacity of anode materials. Si has emerged as a promising anode material due to its huge theoretical specific capacity (4200mAh/g) [3,4], low working potential (about 0.5 V vs Li/Li +) and has low price.…”