composites were successfully synthesized utilizing in situ reactive hot pressing method with Ti, Al, and MoO 3 powders as starting materials. A possible synthesis mechanism was proposed to explain the formation of (Ti,Mo)Al/Al 2 O 3 composites. The investigation results indicate a probable reaction process that molten Al reacted with MoO 3 to form Al 2 O 3 and Mo, and the TiAl matrix grains were refined increasingly by Al 2 O 3 with the addition of MoO 3 increased, accompanying with a small quantity of Mo containing phase AlMoTi 2 formed in the fabricated composites. Meanwhile, the microstructure and mechanical properties of the (Ti,Mo) Al/Al 2 O 3 composites were characterized. The as-synthesized composites exhibited lamellar structure of TiAl intermetallic compound and the in situ formed fine Al 2 O 3 particles dispersed at the stratified TiAl matrix grain boundaries hindering the growth of the grain size of the matrix. And the Rockwell hardness, flexural strength, and fracture toughness of the as-prepared (Ti,Mo) Al/Al 2 O 3 composite were 44.08 HRC, 684 MPa, 7.63 MPaÁm 1/2 , which improved by 57.4%, 107.3%, and 38.7% compared to monolithic TiAl, respectively. The reinforcing mechanism of the material was also discussed.