Effect of nanoscale dielectric environments on concentration quenching

Abstract

We have studied the dependence of concentration quenching of luminescence (donor–acceptor energy transfer) on the thickness d of dye-doped polymeric films (HITC:PMMA) and found its strong inhibition at small values of d. This phenomenon is tentatively explained by a limited number of acceptors, which donors’ excitation can reach in thin samples, if the film’s thickness is comparable to the diffusion length of the energy transfer. The latter mechanism, along with effective reduction of the dye concentration, is responsible for an inhibition of the concentration quenching of dye molecules impregnating porous alumina membranes. The elongation of emission kinetics in thick (≥3 μm) HITC:PMMA films is cautiously attributed to the samples’ crystallinity.

Long-Range Dipole–Dipole Interactions in a Plasmonic Lattice

“…Thus, TPSD serves as a figure of merit to enhance DDIs analogous to LDOS being the figure of merit to enhance spontaneous emission. The subtle differences in dependence of DDIs and spontaneous emission on TPSD and LDOS respectively show that there exists a trade-off between LDOS and TPSD for enhancing either spontaneous emission decay rates or DDIs. ,,,,, …”

“…The subtle differences in dependence of DDIs and spontaneous emission on TPSD and LDOS respectively show that there exists a trade-off between LDOS and TPSD for enhancing either spontaneous emission decay rates or DDIs. 17, 21,22,46,47,48 The dipole−dipole interaction potential strength is related to the dyadic Green's function,…”