raman shift, Ftir spectra and sem were used to detect the percolation threshold of nano titania filler ceramic ntio 2 dispersed in a silicon rubber matrix sr8100 by hot vibrate dispersion. it has been found that an additional frequencies, and stock lines appears in raman shift when ntio 2 reach (5)wt% which mean a change in polarity of the sr8100/ntio 2 Pmnc polarity. keywords: Pmnc, nano ceramic oxide fillers, ntio 2 , raman shift