The intrinsic properties of austenite and ferrite on the mechanical properties and corrosion resistance of the duplex stainless steel weld metals was studied by substituting Ni with Mn, N, and Mn + N. The properties of the weldments fabricated through gas tungsten arc welding (GTAW) were evaluated using tensile test, Vickers hardness, and potentiodynamic polarization tests. The mechanical properties and corrosion resistance of the constituent phases were measured using nanoindentation and electron probe microanalysis, respectively. The austenite and ferrite phase fractions of the weld metal were maintained at approximately 50:50, and no harmful phases degraded the properties. Excessive Mn decreased the corrosion resistance; a large difference in corrosion resistance between austenite and ferrite also decreased the overall corrosion resistance. In the filler metal in which Ni was replaced with only Mn or N, the austenite became harder than ferrite, as a result cracks initiated inside the austenite. The tensile test showed that austenite, which became a relatively hard phase compared to ferrite according to the chemical composition, increased the yield strength and decreased the elongation of the weld metal.