With the development of X-ray computed tomography over the last few decades, it is gradually considered to be a powerful tool in the field of materials research. This paper presents a comprehensive review of applications of CT imaging on fiber reinforced composites, from polymer composites to ceramic matrix composites. The principle of X-ray CT and experimental tomography setups was described firstly. Then, in situ experimental devices developed in recent years were illustrated. Furthermore, the applications of X-ray CT imaging on manufacturing process, modeling, mechanical damage, physical, and chemical behaviors were reviewed in detail. Besides, advantages and limitations of X-ray CT imaging were pointed out and the future development was prospected.