To cite this article: P. Mähnert & B. Linke (2009) Biogas production in agriculture is processed mostly continuously at mesophilic temperatures in completely stirred tank reactors. Therefore, reactor performance data were studied in long-term semi-continuous laboratory-scale experiments with maize silage, whole-crop rye silage and fodder beet silage as mono-substrate and cattle slurry at mesophilic temperatures. For calculation of biogas yield as function of the organic loading rate, a hyperbolic equation was developed on the base of a first-order reaction rate for substrate degradation. The biogas yield depends also on the maximum biogas yield, the concentration of volatile solids of the input, the density of the effluent, the density of the biogas and the reaction rate constant, which are all substrate-or process-specific. Values of the theoretical maximum biogas yield and the reaction rate constant were observed in the range 0.61-0.93 m 3 per kg volatile solids and 0.032 -0.316 d − 1 , respectively. By means of the hyperbolic equation, the proportion of the biogas yield from the maximum can be calculated for the first and a second reactor which also depends on the volume of each reactor.
Keywords: biogas yield; modelling; organic loading rate
IntroductionSince the amendment of the Renewable Energy Sources Act in Germany (Erneuerbare Energien Gesetz) the utilization of energy crops for biogas production has become more cost-effective. The treatment of animal waste slurry and energy crops in co-digestion is a proven technology and recently interest has grown in the potential of using anaerobic processes [1,2]. With respect to energy crops as a single substrate in mono-digestion pioneer work was performed with sorghum ( Sorghum bicolor ), napiergrass ( Pennisetum purpureum ), corn ( Zea mays ), and sorghum/alpha-cellulose in mix experiments about 15 years ago [3]. Further laboratory-, pilotand farm-scale experiments were conducted to obtain kinetic data for anaerobic digestion of energy crops and crop residues [4][5][6][7][8][9][10][11]. Numerous full-scale biogas plants are in operation and digest mainly maize silage, whole crop cereal silage and mixtures of other energy crops.The financial success of a biogas plant results from the quality and the biogas yield of the applied substrate and the process engineering. However, agricultural biogas plants in practice are mostly processed intuitively because the measurement engineering is not improved adequately. Additionally, for energy crops the experience is difficult to generalize because of the great diversity of substrates. Furthermore, high-energetic