Effect of Organoclay Incorporation on Mechanical, Barrier and Thermal Properties and Anti-Bacterial Performance of Pla and Pla Composites with Triclosan and Wood Flour

Prapruddivongs, Chana; Sombatsompop, Narongrit; Jayaraman, Krishnan

doi:10.1177/096739111402200708

Cited by 7 publications

(8 citation statements)

References 21 publications

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“…22 C. Prapruddivongs et al reported higher permeability and antibacterial properties in the samples containing cloisite ® 30B. 23 In the present study, the compatibility of CNC with polylactic acid was improved by chemical surface modification of the nanoparticles with acetic anhydride. The water vapor permeability of CNC/nanosilver-reinforced polylactic acid nanocomposite was also investigated for the first time.…”

Section: Introductionsupporting

confidence: 47%

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Physico-mechanical properties of polylactic acid bio-nanocomposites filled by hybrid nanoparticles

Mirabolghasemi

Najafi

Azizi

et al. 2021

Polymers and Polymer Composites

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This study is aimed to investigate the effect of the simultaneous incorporation of cellulose nanocrystals (CNC) and silver nanoparticles (SN) on the mechanical, biodegradability, and water vapor permeability of polylactic acid (PLA)-based films. PLA films and their nanocomposites containing different levels of CNC (0.333, 1 and 1.667 phr) and SN (0.333 phr) were prepared by solution casting method. CNC was reacted with acetic anhydride to improve its compatibility and miscibility with PLA. Fourier transform infrared (FTIR) spectroscopy, thermogravimetric analysis (TGA), tensile test, and water vapor permeability and antibacterial tests were employed to characterize the samples. The biodegradability was assessed by measuring the weight loss upon burial in the soil. FTIR spectroscopy confirmed the modification of cellulose nanocrystals. TGA test showed that partial acetylation slightly improved the thermal stability of CNC. The presence of cellulose nanocrystals increased the tensile strength and modulus of elasticity of the nanocomposite relative to pure polylactic acid. The biodegradability and water vapor permeability of the samples decreased upon CNC incorporation. The antibacterial properties of the films showed the higher resistance of the gram-positive bacteria as their cell walls include a peptidoglycan layer.

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Section: Introductionsupporting

confidence: 47%

“…22 C. Prapruddivongs et al reported higher permeability and antibacterial properties in the samples containing cloisite® 30B. 23…”

Section: Introductionmentioning

confidence: 99%

Physico-mechanical properties of polylactic acid bio-nanocomposites filled by hybrid nanoparticles

Mirabolghasemi

Najafi

Azizi

et al. 2021

Polymers and Polymer Composites

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“…The obvious decrease on the TS for the samples loaded with CoSiO 2 may be the result of poor bonding interactions between the CoSiO 2 and the PLA matrix. 26 The elongation at break (EB) of PLA and CrPLA containing SiO 2 showed similar behavior that observed in the TS, namely a decrease in the EB as a function of the SiO 2 content. In addition, a significant drop in the EB was observed for the samples composed with CoSiO 2 .…”

Section: Resultsmentioning

confidence: 62%

Effect of surface-modified silica on the thermal and mechanical behaviors of poly(lactic acid) and chemically crosslinked poly(lactic acid) composites

Prapruddivongs

Rukrabiab

Kulwongwit

et al. 2019

Journal of Thermoplastic Composite Materials

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This work studied the properties of poly(lactic acid) (PLA) and chemically crosslinked poly(lactic acid) (CrPLA) in the presence of different types of silica (SiO2): SiO2 from rice husk ash (RhSiO2) and commercially available SiO2 (CoSiO2). A mixture of triallyl isocyanate and dicumyl peroxide was used as a chemical crosslinking agent. The rice husk was burnt in a furnace to extract RhSiO2. The thermal and mechanical properties of the PLA and CrPLA composites were investigated as a function of the SiO2 content. The presence of C–H functional groups supports the compatibility of stearic acid and RhSiO2, thereby facilitating the esterification reaction observed in the Fourier transform infrared-attenuated total reflectance spectra. This played an important role in changing the properties of the PLA-based composites. The concave fracture surfaces were consistent with the tensile results, the thermal properties, and the degree of swelling, which suggested that there was a better reaction between stearic acid and RhSiO2. However, the heat deflection temperatures of both the PLA and the CrPLA composites were not significantly affected by blending with either CoSiO2 or RhSiO2.

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“…In addition, the production and use of biodegradable polymers can also help increase the rate at which fossil fuels increase. Fitria et al (2020), Prapruddivongs et al (2014), Sun and Pei (2017).…”

Section: Introductionmentioning

confidence: 99%

Promotion of Polylactid Acid Eco-Friendly by Combined Addition of PCL Catechin-Chitosan Under Extruding Condition

Suryani¹,

Rihayat²,

Setiawati³

et al. 2021

Int. J. Res. Granthaalayah

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Biodegradable polymers are seen as a potential solution for the environment generated by plastic waste. The purpose of this study was to see the effect of adding a catalyst to the manufacture of PLA/PCL-Catechin-Chitosan as a raw material for making plastics . This research was carried out with variations in the addition of ZnO catalyst 0.1 % (PPXya), 0.2% (PPXyb) and 0.3% (PPXyc ). From the results of the analysis using Fourier Transform Infrared (FTIR) obtained stretching groups of OH, CO and C= O at wavelengths (3860, 1060 and 1753) cm-1 at the addition of 0.3% ZnO catalyst (PPXyc ). Based on the analysis of the thermal stability using Thermogravimetry (TGA) the decomposition temperature was obtained at 387℃ with the addition of catalyst 0.3% (PPXyc ). Morphological analysis using Scanning Electron Microscopy (SEM) showed that the surface structure of PLA was in the form of widespread lumps. The more concentration of additional catalyst used can affect the formation of PLA/PCL-Catechin-Chitosan. The result of the tensile test tensile analysus are greater the addition of ZnO catalyst in the sample PLA-PCL-Catechin-hitosan can to be able to increase the tensile value of the of the sample.

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Effect of Organoclay Incorporation on Mechanical, Barrier and Thermal Properties and Anti-Bacterial Performance of Pla and Pla Composites with Triclosan and Wood Flour

Cited by 7 publications

References 21 publications

Physico-mechanical properties of polylactic acid bio-nanocomposites filled by hybrid nanoparticles

Physico-mechanical properties of polylactic acid bio-nanocomposites filled by hybrid nanoparticles

Effect of surface-modified silica on the thermal and mechanical behaviors of poly(lactic acid) and chemically crosslinked poly(lactic acid) composites

Promotion of Polylactid Acid Eco-Friendly by Combined Addition of PCL Catechin-Chitosan Under Extruding Condition

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