Effect of outer sphere acetate ion association on the methanol exchange rate of CO(MeOH)3O2CMe+

Kurtz, James L.; Vriesenga, Jack R.

doi:10.1039/c3974000711b

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The Mechanistic Role Of Outer Sphere Complexes1

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1988

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“…Thus polarization of the carbonyl bond by first sphere binding increases its susceptibility to nucleophilic attack whereas appropriate hydrogen bonding could increase the nucleophilicity of the aniline. Direct evidence for change in the reactivity of a first sphere ligand (methanol) due to the presence of a second sphere ligand (acetate ion) has been presented by Kurtz and Vriesenga [89].…”

Section: The Mechanistic Role Of Outer Sphere Complexesmentioning

confidence: 97%

Outer sphere complexes as intermediates in coordination chemistry

Eaton

1988

Reviews of Chemical Intermediates

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Section: The Mechanistic Role Of Outer Sphere Complexesmentioning

confidence: 97%

Outer sphere complexes as intermediates in coordination chemistry

Eaton

1988

Reviews of Chemical Intermediates

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Zur Reaktion von Aluminium(III) mit 7‐Iod‐chinolin‐8‐ol‐5‐sulfonsäure (Ferron) in wäßriger Lösung

Nitzsche¹,

Mitzner²,

Röbisch³

et al. 1987

Zeitschrift anorg allge chemie

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Unter den Bedingungen der Aluminium‐Ferron‐Reaktion wird der Komplex AlL2− gebildet. Die Verbesserung der kinetischen Meßmethodik gestattete die exakte Untersuchung des Zeitbereiches t≤2 min, in dem nach bisheriger Meinung nur monomere Al(III)‐Spezies mit Ferron reagieren sollten. Das Auftreten eines Knickes im Kurvenverlauf des lg (E∞ – Ei)/t‐Diagramms bei pH ≥ 4 wird durch die Einbeziehung Dimerer in die Reaktion verständlich. Das Vorliegen einer allgemeinen Basenkatalyse wird nachgewiesen und ein Reaktionsmodell beschrieben.

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