2013
DOI: 10.1002/crat.201200514
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Effect of oxygen partial pressure on the marangoni flow of molten metals

Abstract: Key words surface tension, silver, iron, Marangoni flow, boomerang, oxygen partial pressure.Measurements of surface tension of molten silver and iron are reviewed. Surface tension of molten silver and iron show boomerang-shaped behavior; the maximum surface tension appears at a certain temperature, below which temperature coefficient of surface tension is positive. Due to change of temperature coefficient, Marangoni flow direction shows variation in a liquid bridge configuration.

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Cited by 11 publications
(6 citation statements)
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“…The relevant curve for a sulfur concentration of 150 ppm is plotted in figure 2. Experimentally, such a behaviour with a sign change at a critical temperature has been shown to occur in steels [42,43] and pure iron [44], as well as other metals such as silver [44] and nickel [45].…”
Section: Momentummentioning
confidence: 94%
“…The relevant curve for a sulfur concentration of 150 ppm is plotted in figure 2. Experimentally, such a behaviour with a sign change at a critical temperature has been shown to occur in steels [42,43] and pure iron [44], as well as other metals such as silver [44] and nickel [45].…”
Section: Momentummentioning
confidence: 94%
“…A realistic relationship 10,25 between the surface tension temperature coefficient ∂γ/∂T and temperature for a binary liquid metal -surfactant mixture, as shown in figure 2, will be used in the simulations:…”
Section: B Boundary Conditionsmentioning
confidence: 99%
“…The shape of the surface tension-temperature curve and thus the system behavior is not specific to the iron-sulfur system, but also applies to e.g. silver 25 and nickel 26 in the presence of oxygen.…”
Section: B Boundary Conditionsmentioning
confidence: 99%
“…[ 110–112 ] Further effects like O absorption could also have a decisive influence on the surface tension. [ 110,113 ] However, under the assumption of higher surface tension for Ag than for AgCaLa, a reduced difference in surface tension between Fe and Ag, compared to Fe and AgCaLa, is conclusive. This reduces the necessary surface energy and the formation of narrow Ag phases with a large surface is simplified.…”
Section: Resultsmentioning
confidence: 99%