Effect of phonon energy on 2 μm emission in Tm3+/Yb3+ co-doped bismuth-tellurite glasses based on WO3 or B2O3 adjustment

Song, Chunlai; Xu, Pengfei; Zhou, Dechun; Zhang, Kexin; Ma, Bo; Cong, Yuxuan; Bai, Yuerong; Cao, Jilong; Han, Kexuan

doi:10.1016/j.jlumin.2022.119610

Cited by 3 publications

(1 citation statement)

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“…It has been shown that incorporation of higher phonon energy oxides can aide in this process. 37 Emission in this region is based on co-doping of Yb 3+ ions with Tm 3+ /Ho 3+ ions and the subsequent energy transfer between them. It has been shown that incorporation of higher phonon energy components into tellurite glass alters the ligand field environment around rare earth ions and improves the multi-phonon decay thereby increasing 2 μm emission.…”

Section: Optical Applications Of Bismuth Tellurite Glassesmentioning

confidence: 99%

Review—Recent Advances in Bismuth Tellurite Glasses for Photonic and Radiation Shielding Applications

Blessy Kamalam,

Manikandan

2023

ECS J. Solid State Sci. Technol.

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The inherent properties of heavy metal oxide glasses have led to their widespread applications in various domains including lasers, optical fibers, optoelectronics, and radiation shielding materials. Tellurium oxide and bismuth oxides are conditional glass forming heavy metal oxides which, when combined, suitably yield significant improvement in the whole system. Lower phonon energy of tellurite helps in aiding broader transmission and lasing properties, while the ability of bismuth ions to reside in various valence states aids in incorporation of optically active rare earth ions in these glasses. The near infrared emission characteristic of bismuth ions could be improved by co-doping with rare earth ions to improve the emission and consequently their applications as photonic devices. Higher density of these oxides helps in increasing the radiation shielding ability, thereby making them suitable replacement materials for lead based toxic compounds.

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Section: Optical Applications Of Bismuth Tellurite Glassesmentioning

confidence: 99%