Introduction Non-intelligent factors include learning habits, motivation, interest, emotion, attitude, and student characteristics. Many sports practices have demonstrated that creating excellent athletic performance and winning intense competition depends on various factors. Among them, physical quality is the physiological and material basis to ensure the quality of exercise. Movement technique is the essential condition. However, non-Intelligent factors are the internal motivators for both to function. Objective Analyze the non-Intelligent factors that affect the performance of volleyball players. Methods Several volleyball players were selected as research objects. The non-Intelligent factors that affect volleyball performance are analyzed by questionnaire survey and experimental method. Finally, this paper uses mathematical statistics to analyze the experimental data. Results Volleyball players are easily disturbed by external factors. These non-Intelligent factors can easily lead to large fluctuations in the athlete’s psychology. These reasons will affect the stability of volleyball players’ serving skills. Conclusion The non-Intelligent factors that affect the performance of volleyball players are the proficiency of serving technique, the degree of psychological relaxation, and the ability of emotional control. Level of evidence II; Therapeutic studies - investigation of treatment results.