2023
DOI: 10.3389/fnut.2023.1174888
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Effect of physiological pH on the molecular characteristics, rheological behavior, and molecular dynamics of κ-carrageenan/casein

Abstract: IntroductionDuring gastrointestinal digestion, κ-carrageenan (κ-CGN) undergoes physicochemical changes, which associated with the risk of colitis.MethodsTo understand the effect of physiological pH on the conformational transition and binding stability of κ-CGN and κ-carrageenan/casein (κ-CC), we conducted experiments at pH 3.0 (gastric environment) and pH 7.0 (intestinal environment). We evaluated zeta potential, free sulfate group content, Fourier transform infrared spectroscopy, thermodynamic properties, mi… Show more

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Cited by 4 publications
(2 citation statements)
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“…The specific sharp peaks at 923 cm −1 and 846 cm −1 are assigned to the 3,6-anhydro-galactose residue and D-galactose-4-sulphate, respectively. In addition, intensive bands between 1148 and 1028 cm -−1 , and 800 and 700 cm −1 , are presumably attributed to the stretching and bending in pyranose units within polysaccharide chains [81,82].…”
Section: Atr-ftirmentioning
confidence: 99%
“…The specific sharp peaks at 923 cm −1 and 846 cm −1 are assigned to the 3,6-anhydro-galactose residue and D-galactose-4-sulphate, respectively. In addition, intensive bands between 1148 and 1028 cm -−1 , and 800 and 700 cm −1 , are presumably attributed to the stretching and bending in pyranose units within polysaccharide chains [81,82].…”
Section: Atr-ftirmentioning
confidence: 99%
“…Carrageenan belongs to the group of linear polysaccharides that have sulfur groups in their chains. Polysaccharides mainly consist of galactose (3,6-anhydride-galactose and Dgalactose) and ester sulfates, both of which make up the structural backbone [8,22]. Lambda (λ), kappa (κ), and iota (i) are the three main types of carrageenans and are distinguished by the sulfate group present in the repeat unit [14].…”
Section: Physicochemical and Structural Properties Of Carrageenanmentioning
confidence: 99%