“…This remarkable transition is accompanied by a large modification of its electrical and optical properties: the electrical resistivity decreases by several orders of magnitude between the semiconductor and the metallic states while the reflectivity in the near-infrared optical domain increases (Zylbersztejn & Mott, 1975;Verleur et al, 1968). The reversible SMT transition can be triggered by different external excitations: temperature, optically (Cavalleri et al, 2001(Cavalleri et al, , 2004(Cavalleri et al, , 2005Ben-Messaoud et al, 2008;Lee et al, 2007), electrically-by charge injection (Stefanovich et al, 2000; Exploiting the semiconductor-metal phase transition of VO2 materials: a novel direction towards tuneable devices and systems for RFmicrowave applications 37 Guzman et al, 1996 and even pressure (Sakai & Kurisu, 2008). Recent studies showed that the electrically-and optically-induced transitions can occur very fast (Stefanovich et al, 2000;Cavalleri et al, 2001Cavalleri et al, -2005) (down to 100 fs for the optically-triggered ones (Cavalleri et al, 2005)) and that the transition is more typical of a rearrangement of the electrons in the solid (electron-electron correlations) than it is a an atomic rearrangement (crystalline phase transition from semiconductor monoclinic to a metallic rutile structure).…”